Cyclo(alanylalanylglycylleucylprolyltryptophylleucylisoleucyl)

9-(butan-2-yl)-3-[(1H-indol-3-yl)methyl]-12,15-dimethyl-6,21-bis(2-methylpropyl)-hexacosahydropyrrolo[1,2-a]1,4,7,10,13,16,19,22-octaazacyclotetracosan-1,4,7,10,13,16,19,22-octone

Formula: C42H63N9O8 (821.4799)
Chinese Name:
BioDeep ID: BioDeep_00000228475 ( View LC/MS Profile)
SMILES: CCC(C)C1NC(=O)C(CC(C)C)NC(=O)C(CC2=CNC3=CC=CC=C23)NC(=O)C2CCCN2C(=O)C(CC(C)C)NC(=O)CNC(=O)C(C)NC(=O)C(C)NC1=O



Found 8 Sample Hits

m/z Adducts Species Organ Scanning Sample
804.4873 [M+H-H2O]+
PPM:13.2		 Mus musculus Lung MALDI (DHB)
image2 - MTBLS2075
Resolution: 40μm, 550x256

Description

Supplementary Figure S6. Ion distribution images for (a) [PC36:4+Na]+ (m/z 804.5514) and (b) [PC38:6+Na]+ (m/z 828.5515) obtained from mouse lung tissue collected 6 h after administration of D9- choline and U13C-DPPC–containing CHF5633. Parts-per-million (ppm) mass errors are indicated in parentheses. (c) Magnification of the boxed region in (a) with selected bronchiolar regions outlined in white boxes. (d) The corresponding H&E-stained tissue section with the same selected bronchiolar regions outlined in black boxes. These data demonstrate the co-localisation of the polyunsaturated lipids PC36:4 and PC38:6 with the bronchiolar regions of the lung. All MSI images were visualised using total ion current normalisation and hotspot removal (high quantile = 99%).
822.4842 [M+H]+
PPM:3.7		 Homo sapiens esophagus DESI ()
LNTO22_1_7 - MTBLS385
Resolution: 75μm, 69x54

Description

804.4728 [M+H-H2O]+
PPM:4.8		 Homo sapiens esophagus DESI ()
LNTO22_1_8 - MTBLS385
Resolution: 75μm, 69x61

Description

822.4818 [M+H]+
PPM:6.6		 Mus musculus brain MALDI (DHB)
Brain02_Bregma1-42_03 - MTBLS313
Resolution: 17μm, 483x403

Description

804.4716 [M+H-H2O]+
PPM:6.3		 Homo sapiens colorectal adenocarcinoma DESI ()
240TopL, 210TopR, 230BottomL, 220BottomR-centroid - MTBLS176
Resolution: 50μm, 142x141

Description

822.4828 [M+H]+
PPM:5.4		 Homo sapiens colorectal adenocarcinoma DESI ()
240TopL, 210TopR, 230BottomL, 220BottomR-centroid - MTBLS176
Resolution: 50μm, 142x141

Description

804.4722 [M+H-H2O]+
PPM:5.5		 Homo sapiens colorectal adenocarcinoma DESI ()
200TopL, 170TopR, 190BottomL, 180BottomR-centroid - MTBLS176
Resolution: 50μm, 132x126

Description

822.4832 [M+H]+
PPM:4.9		 Homo sapiens colorectal adenocarcinoma DESI ()
200TopL, 170TopR, 190BottomL, 180BottomR-centroid - MTBLS176
Resolution: 50μm, 132x126

Description


Constituent of the fruit peel of Citrus medica variety sarcodactylis. Cyclo(alanylalanylglycylleucylprolyltryptophylleucylisoleucyl) is found in citrus.