- Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
- Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
- Unreliable: 这个参考离子具有较高的排名价值,但缺乏可重复性。
- Unavailable: 由于排名价值低且缺乏可重复性,这个参考离子不应用于注释。
Found 10 Reference Ions Near m/z 221.1538
NovoCell ID | m/z | Mass Window | Metabolite | Ranking | Anatomy Context |
---|---|---|---|---|---|
MSI_000056402 Reliable | 221.1535 | 221.1531 ~ 221.1539 MzDiff: 3.4 ppm |
Acetyl-L-carnitine (BioDeep_00000018395) Formula: C9H17NO4 (203.1158) |
6.14 (100%) | DESI [NOVOCELL:BACKGROUND] blank |
MSI_000065701 Reliable | 221.1543 | 221.1541 ~ 221.1544 MzDiff: 1.5 ppm |
3,4-Dihydroxyhydrocinnamic acid (BioDeep_00000003369) Formula: C9H10O4 (182.0579) |
1.77 (67%) | Homo sapiens [UBERON:0001155] colon |
MSI_000052694 Unreliable | 221.1553 | 221.1551 ~ 221.1554 MzDiff: 1.3 ppm |
3,4-Dihydroxyhydrocinnamic acid (BioDeep_00000003369) Formula: C9H10O4 (182.0579) |
3.72 (100%) | DESI [NOVOCELL:BACKGROUND] blank |
MSI_000065958 Unreliable | 221.1536 | 221.1531 ~ 221.1539 MzDiff: 3.4 ppm |
Acetyl-L-carnitine (BioDeep_00000018395) Formula: C9H17NO4 (203.1158) |
0.98 (100%) | Homo sapiens [UBERON:0007779] transudate |
MSI_000041039 Unreliable | 221.1512 | 221.1511 ~ 221.1515 MzDiff: 1.5 ppm |
13-Nor-6-eremophilene-8,11-dione (BioDeep_00000021799) Formula: C14H20O2 (220.1463) |
1.6 (67%) | Posidonia oceanica [PO:0006036] root epidermis |
MSI_000053559 Unreliable | 221.1554 | 221.1554 ~ 221.1554 MzDiff: none |
3,4-Dihydroxyhydrocinnamic acid (BioDeep_00000003369) Formula: C9H10O4 (182.0579) |
2.26 (100%) | DESI [NOVOCELL:BACKGROUND] blank |
MSI_000055723 Unreliable | 221.1547 | 221.1544 ~ 221.1549 MzDiff: 2.1 ppm |
3,4-Dihydroxyhydrocinnamic acid (BioDeep_00000003369) Formula: C9H10O4 (182.0579) |
0.97 (100%) | Homo sapiens [UBERON:0007779] transudate |
MSI_000039054 Unreliable | 221.1513 | 221.1512 ~ 221.1515 MzDiff: 1.2 ppm |
Homovanillic acid (HVA) (BioDeep_00000017338) Formula: C9H10O4 (182.0579) |
1.12 (50%) | Posidonia oceanica [PO:0005059] root endodermis |
MSI_000043607 Unreliable | 221.1528 | 221.1528 ~ 221.1528 MzDiff: none |
Acetyl-L-carnitine (BioDeep_00000018395) Formula: C9H17NO4 (203.1158) |
1.4 (100%) | Homo sapiens [UBERON:0001043] esophagus |
MSI_000035428 Unreliable | 221.151 | 221.151 ~ 221.151 MzDiff: none |
13-Nor-6-eremophilene-8,11-dione (BioDeep_00000021799) Formula: C14H20O2 (220.1463) |
0.16 (100%) | Posidonia oceanica [PO:0006203] pericycle |
Found 44 Sample Hits
Metabolite | Species | Sample | |
---|---|---|---|
Acetyl-L-carnitine Formula: C9H17NO4 (203.1158) Adducts: [M+NH4]+ (Ppm: 19.5) |
Marker Pen (NA) |
3ul_0.8Mpa_RAW_20241016-PAPER PNMKResolution: 30μm, 315x42
By writing the four English letters “PNMK” on white paper with a marker pen, and then scanning with a DESI ion source to obtain the scanning result. The signal of the chemical substances on the marker pen used appears on the channel with an m/z value of |
|
13-Nor-6-eremophilene-8,11-dione Formula: C14H20O2 (220.1463) Adducts: [M+H]+ (Ppm: 11.7) |
Posidonia oceanica (root) |
20190614_MS1_A19r-20Resolution: 17μm, 262x276
Seagrasses are one of the most efficient natural sinks of carbon dioxide (CO2) on Earth. Despite covering less than 0.1% of coastal regions, they have the capacity to bury up to 10% of marine organic matter and can bury the same amount of carbon 35 times faster than tropical rainforests. On land, the soil’s ability to sequestrate carbon is intimately linked to microbial metabolism. Despite the growing attention to the link between plant production, microbial communities, and the carbon cycle in terrestrial ecosystems, these processes remain enigmatic in the sea. Here, we show that seagrasses excrete organic sugars, namely in the form of sucrose, into their rhizospheres. Surprisingly, the microbial communities living underneath meadows do not fully use this sugar stock in their metabolism. Instead, sucrose piles up in the sediments to mM concentrations underneath multiple types of seagrass meadows. Sediment incubation experiments show that microbial communities living underneath a meadow use sucrose at low metabolic rates. Our metagenomic analyses revealed that the distinct community of microorganisms occurring underneath meadows is limited in their ability to degrade simple sugars, which allows these compounds to persist in the environment over relatively long periods of time. Our findings reveal how seagrasses form blue carbon stocks despite the relatively small area they occupy. Unfortunately, anthropogenic disturbances are threatening the long-term persistence of seagrass meadows. Given that these sediments contain a large stock of sugars that heterotopic bacteria can degrade, it is even more important to protect these ecosystems from degradation. |
|
Homovanillic acid (HVA) Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 18.8) |
Posidonia oceanica (root) |
20190613_MS1_A19r-18Resolution: 17μm, 246x264
|
|
13-Nor-6-eremophilene-8,11-dione Formula: C14H20O2 (220.1463) Adducts: [M+H]+ (Ppm: 11.3) |
Posidonia oceanica (root) |
20190828_MS1_A19r-22Resolution: 17μm, 292x279
|
|
13-Nor-6-eremophilene-8,11-dione Formula: C14H20O2 (220.1463) Adducts: [M+H]+ (Ppm: 10.8) |
Posidonia oceanica (root) |
MS1_20180404_PO_1200Resolution: 17μm, 193x208
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 4.3) |
Homo sapiens (esophagus) |
LNTO22_1_3Resolution: 75μm, 121x68
|
|
Acetyl-L-carnitine Formula: C9H17NO4 (203.1158) Adducts: [M+NH4]+ (Ppm: 19.5) |
Homo sapiens (esophagus) |
LNTO22_1_4Resolution: 17μm, 82x80
|
|
Acetyl-L-carnitine Formula: C9H17NO4 (203.1158) Adducts: [M+NH4]+ (Ppm: 17.3) |
Homo sapiens (esophagus) |
LNTO29_16_2Resolution: 17μm, 95x101
|
|
13-Tetradecene-1,3-diyne-6,7-diol Formula: C14H20O2 (220.1463) Adducts: [M+H]+ (Ppm: 2.7) |
Homo sapiens (esophagus) |
TO42TResolution: 17μm, 69x81
|
|
Acetyl-L-carnitine Formula: C9H17NO4 (203.1158) Adducts: [M+NH4]+ (Ppm: 14.6) |
Homo sapiens (esophagus) |
LNTO22_1_9Resolution: 75μm, 89x74
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 6.1) |
Homo sapiens (esophagus) |
LNTO30_8M_1Resolution: 17μm, 69x54
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 5.7) |
Homo sapiens (esophagus) |
TO39TResolution: 17μm, 69x81
|
|
Acetyl-L-carnitine Formula: C9H17NO4 (203.1158) Adducts: [M+NH4]+ (Ppm: 0.4) |
Homo sapiens (colorectal adenocarcinoma) |
80TopL, 50TopR, 70BottomL, 60BottomR-profileResolution: 17μm, 137x136
The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024). |
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 1.2) |
Homo sapiens (colorectal adenocarcinoma) |
80TopL, 50TopR, 70BottomL, 60BottomR-profileResolution: 17μm, 137x136
The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024). |
|
Acetyl-L-carnitine Formula: C9H17NO4 (203.1158) Adducts: [M+NH4]+ (Ppm: 2.4) |
Homo sapiens (colorectal adenocarcinoma) |
520TopL, 490TopR, 510BottomL, 500BottomR-profileResolution: 17μm, 147x131
The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024). |
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 1.6) |
Homo sapiens (colorectal adenocarcinoma) |
520TopL, 490TopR, 510BottomL, 500BottomR-profileResolution: 17μm, 147x131
The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024). |
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 5.2) |
Homo sapiens (colorectal adenocarcinoma) |
439TopL, 409TopR, 429BottomL, 419BottomR-profileResolution: 17μm, 157x136
The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024). |
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 6.1) |
Homo sapiens (NA) |
160TopL,130TopR,150BottomL,140BottomR-profileResolution: 17μm, 142x136
|
|
Acetyl-L-carnitine Formula: C9H17NO4 (203.1158) Adducts: [M+NH4]+ (Ppm: 15.9) |
Homo sapiens (esophagus) |
LNTO29_16_3Resolution: 17μm, 108x107
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 4.3) |
Homo sapiens (esophagus) |
LNTO26_7_1Resolution: 17μm, 75x74
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 3.4) |
Homo sapiens (esophagus) |
LNTO26_7_2Resolution: 17μm, 135x101
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 4.8) |
Homo sapiens (esophagus) |
LNTO26_7_3Resolution: 75μm, 82x88
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 7) |
Homo sapiens (esophagus) |
TO40TResolution: 17μm, 82x74
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 5.7) |
Homo sapiens (esophagus) |
TO31TResolution: 75μm, 56x54
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 4.3) |
Homo sapiens (esophagus) |
TO29TResolution: 75μm, 56x48
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 4.8) |
Homo sapiens (esophagus) |
TO41TResolution: 75μm, 69x43
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 6.1) |
Homo sapiens (esophagus) |
LNTO30_8M_2Resolution: 75μm, 108x68
|
|
13-Tetradecene-1,3-diyne-6,7-diol Formula: C14H20O2 (220.1463) Adducts: [M+H]+ (Ppm: 2.3) |
Homo sapiens (esophagus) |
LNTO30_8M_3Resolution: 75μm, 69x54
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 5.2) |
Homo sapiens (esophagus) |
LNTO30_8M_4Resolution: 75μm, 62x48
|
|
13-Tetradecene-1,3-diyne-6,7-diol Formula: C14H20O2 (220.1463) Adducts: [M+H]+ (Ppm: 2.3) |
Homo sapiens (esophagus) |
LNTO30_8M_5Resolution: 75μm, 56x54
|
|
Acetyl-L-carnitine Formula: C9H17NO4 (203.1158) Adducts: [M+NH4]+ (Ppm: 18.2) |
Homo sapiens (esophagus) |
LNTO30_17_2Resolution: 75μm, 82x54
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 4.3) |
Homo sapiens (esophagus) |
LNTO22_1_5Resolution: 75μm, 135x94
|
|
Acetyl-L-carnitine Formula: C9H17NO4 (203.1158) Adducts: [M+NH4]+ (Ppm: 13.7) |
Homo sapiens (esophagus) |
LNTO22_1_7Resolution: 75μm, 69x54
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 4.3) |
Homo sapiens (esophagus) |
LNTO22_1_8Resolution: 75μm, 69x61
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 4.3) |
Homo sapiens (esophagus) |
LNTO22_2_1Resolution: 75μm, 89x88
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 2.5) |
Homo sapiens (esophagus) |
LNTO22_2_2Resolution: 75μm, 135x94
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 4.3) |
Homo sapiens (esophagus) |
LNTO26_16_1Resolution: 75μm, 95x88
|
|
Acetyl-L-carnitine Formula: C9H17NO4 (203.1158) Adducts: [M+NH4]+ (Ppm: 19.1) |
Homo sapiens (esophagus) |
LNTO29_18_2Resolution: 75μm, 62x68
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 6.1) |
Homo sapiens (esophagus) |
LNTO30_7_1Resolution: 75μm, 69x68
|
|
13-Tetradecene-1,3-diyne-6,7-diol Formula: C14H20O2 (220.1463) Adducts: [M+H]+ (Ppm: 3.2) |
Homo sapiens (esophagus) |
LNTO30_7_2Resolution: 75μm, 82x68
|
|
Acetyl-L-carnitine Formula: C9H17NO4 (203.1158) Adducts: [M+NH4]+ (Ppm: 19.5) |
Homo sapiens (colorectal adenocarcinoma) |
240TopL, 210TopR, 230BottomL, 220BottomR-centroidResolution: 50μm, 142x141
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 5.7) |
Homo sapiens (colorectal adenocarcinoma) |
200TopL, 170TopR, 190BottomL, 180BottomR-centroidResolution: 50μm, 132x126
|
|
3,4-Dihydroxyhydrocinnamic acid Formula: C9H10O4 (182.0579) Adducts: [M+K]+ (Ppm: 6.1) |
Homo sapiens (colorectal adenocarcinoma) |
160TopL,130TopR,150BottomL,140BottomR-centroidResolution: 50μm, 142x136
|
|
13-Tetradecene-1,3-diyne-6,7-diol Formula: C14H20O2 (220.1463) Adducts: [M+H]+ (Ppm: 2.3) |
Homo sapiens (colorectal adenocarcinoma) |
120TopL, 90TopR, 110BottomL, 100BottomR-centroidResolution: 50μm, 132x136
|
|