M/Z: 586.2306

Hit 3 annotations: Montelukast_[M+H]+; 9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione_[M+H]+; 9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione_[M+H]+

在BioDeep NovoCell知识数据库中，参考离子总共被划分为4个级别。

Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
Unreliable: 这个参考离子具有较高的排名价值，但缺乏可重复性。
Unavailable: 由于排名价值低且缺乏可重复性，这个参考离子不应用于注释。

Found 7 Reference Ions Near m/z 586.2306

NovoCell ID	m/z	Mass Window	Metabolite	Ranking	Anatomy Context
MSI_000063117 Reliable	586.2303	586.2302 ~ 586.2303 MzDiff: `0.2 ppm`	9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione (BioDeep_00000172564) Formula: C30H35NO11 (585.221)	2.14 (100%)	Mus musculus [UBERON:0000956] cerebral cortex
MSI_000061137 Unreliable	586.2317	586.2317 ~ 586.2317 MzDiff: `0.1 ppm`	9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione (BioDeep_00000172564) Formula: C30H35NO11 (585.221)	3.29 (100%)	Mus musculus [UBERON:0000956] cerebral cortex
MSI_000022206 Unreliable	586.228	586.228 ~ 586.228 MzDiff: `none`	Montelukast (BioDeep_00000002541) Formula: C35H36ClNO3S (585.2104)	0.36 (100%)	Mus musculus [UBERON:0001499] muscle of arm
MSI_000058839 Unreliable	586.2306	586.2302 ~ 586.2309 MzDiff: `2.6 ppm`	9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione (BioDeep_00000172564) Formula: C30H35NO11 (585.221)	0.81 (100%)	Mus musculus [UBERON:0001950] neocortex
MSI_000060154 Unavailable	586.2309	586.2309 ~ 586.2309 MzDiff: `none`	9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione (BioDeep_00000172564) Formula: C30H35NO11 (585.221)	-1.09 (100%)	Mus musculus [UBERON:0002298] brainstem
MSI_000060282 Unreliable	586.2309	586.2309 ~ 586.2309 MzDiff: `none`	9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione (BioDeep_00000172564) Formula: C30H35NO11 (585.221)	0.87 (100%)	Mus musculus [UBERON:0002421] hippocampal formation
MSI_000065905 Unreliable	586.2318	586.2318 ~ 586.2318 MzDiff: `none`	9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione (BioDeep_00000172564) Formula: C30H35NO11 (585.221)	1.15 (100%)	Homo sapiens [UBERON:0007779] transudate

Found 13 Sample Hits

Metabolite	Species	Sample
Montelukast Formula: C35H36ClNO3S (585.2104) Adducts: [M+H]+ (Ppm: 17.6)	Mus musculus (Left upper arm)	357_l_total ion count Resolution: 50μm, 97x131 Description Diseased
9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione Formula: C30H35NO11 (585.221) Adducts: [M+H]+ (Ppm: 2.3)	Mus musculus (Lung)	image3 Resolution: 40μm, 146x190 Description Fig. 4 MALDI-MSI data of mouse lung tissue after administration with D9-choline and U13C-DPPC–containing Poractant alfa surfactant (labels administered 12 h prior to tissue collection). Ion images of (A) m/z 796.6856 ([U13C-DPPC+Na]+), (B) m/z 756.5154 [PC32:0+Na]+), and (C) m/z 765.6079 ([D9-PC32:0+Na]+). D: Overlay image of [U13C-PC32:0+Na]+ (red) and [D9-PC32:0+Na]+ (green). Part-per-million (ppm) mass errors are indicated in parentheses. All images were visualized using total-ion-current normalization and using hotspot removal (high quantile = 99%). DPPC = PC16:0/16:0. MSI, mass spectrometry imaging; PC, phosphatidylcholine; U13C-DPPC, universally 13C-labeled dipalmitoyl PC.
9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione Formula: C30H35NO11 (585.221) Adducts: [M+H]+ (Ppm: 4)	Mytilus edulis (gill)	20190202_MS38_Crassostrea_Gill_350-1500_DHB_pos_A25_11um_305x210 Resolution: 11μm, 305x210 Description single cell layer `class_4` is the gill structure cells, metabolite ion 534.2956 is the top representive ion of this type of cell
9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione Formula: C30H35NO11 (585.221) Adducts: [M+H]+ (Ppm: 4)	Mytilus edulis (mantle)	20190216_MS38_Mytilus_mantle_350-1500_DHB_pos_A26_10um_275x210 Resolution: 10μm, 275x210 Description
9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione Formula: C30H35NO11 (585.221) Adducts: [M+H]+ (Ppm: 7.7)	Homo sapiens (esophagus)	LNTO22_2_1 Resolution: 75μm, 89x88 Description
9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione Formula: C30H35NO11 (585.221) Adducts: [M+H]+ (Ppm: 4.5)	Mus musculus (brain)	Brain01_Bregma-3-88b_centroid Resolution: 17μm, 265x320 Description
9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione Formula: C30H35NO11 (585.221) Adducts: [M+H]+ (Ppm: 5.8)	Mus musculus (brain)	Brain01_Bregma1-42_01_centroid Resolution: 17μm, 447x118 Description
9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione Formula: C30H35NO11 (585.221) Adducts: [M+H]+ (Ppm: 3.5)	Mus musculus (brain)	Brain02_Bregma1-42_03 Resolution: 17μm, 483x403 Description
9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione Formula: C30H35NO11 (585.221) Adducts: [M+H]+ (Ppm: 3.3)	Mus musculus (brain)	Brain02_Bregma-3-88 Resolution: 17μm, 288x282 Description
9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione Formula: C30H35NO11 (585.221) Adducts: [M+H]+ (Ppm: 3.3)	Mus musculus (brain)	Brain02_Bregma-1-46 Resolution: 17μm, 294x399 Description
9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione Formula: C30H35NO11 (585.221) Adducts: [M+H]+ (Ppm: 6)	Homo sapiens (colorectal adenocarcinoma)	240TopL, 210TopR, 230BottomL, 220BottomR-centroid Resolution: 50μm, 142x141 Description
9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione Formula: C30H35NO11 (585.221) Adducts: [M+H]+ (Ppm: 5.2)	Homo sapiens (colorectal adenocarcinoma)	160TopL,130TopR,150BottomL,140BottomR-centroid Resolution: 50μm, 142x136 Description
9-Ethyl-4,6,9,10,11-pentahydroxy-7-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-morpholin-4-yloxan-2-yl]oxy-8,10-dihydro-7H-tetracene-5,12-dione Formula: C30H35NO11 (585.221) Adducts: [M+H]+ (Ppm: 6.7)	Homo sapiens (colorectal adenocarcinoma)	120TopL, 90TopR, 110BottomL, 100BottomR-centroid Resolution: 50μm, 132x136 Description