M/Z: 989.5948

Hit 1 annotations: n-[1-({1-[2-({1-[(1-{[3-(4-methoxyphenyl)-1-oxo-1-[2-(1,3-thiazol-2-yl)pyrrolidin-1-yl]propan-2-yl](methyl)carbamoyl}-2-methylpropyl)(methyl)carbamoyl]-2-methylpropyl}(methyl)carbamoyl)pyrrolidin-1-yl]-3-methyl-1-oxobutan-2-yl}(methyl)carbamoyl)ethyl]-n-methyloct-7-ynamide_[M+H]+

在BioDeep NovoCell知识数据库中，参考离子总共被划分为4个级别。

Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
Unreliable: 这个参考离子具有较高的排名价值，但缺乏可重复性。
Unavailable: 由于排名价值低且缺乏可重复性，这个参考离子不应用于注释。

Found 25 Reference Ions Near m/z 989.5948

NovoCell ID	m/z	Mass Window	Metabolite	Ranking	Anatomy Context
MSI_000061315 Reliable	989.6035	989.6033 ~ 989.6036 MzDiff: `1.1 ppm`	hemicalyculin A (BioDeep_00000179704) Formula: C52H85N4O12P (988.5901)	0.85 (100%)	Mus musculus [UBERON:0000956] cerebral cortex
MSI_000058513 Unreliable	989.6033	989.6033 ~ 989.6034 MzDiff: `0.6 ppm`	hemicalyculin A (BioDeep_00000179704) Formula: C52H85N4O12P (988.5901)	1.86 (100%)	Mus musculus [UBERON:0001950] neocortex
MSI_000062930 Unreliable	989.6046	989.6046 ~ 989.6046 MzDiff: `none`	hemicalyculin A (BioDeep_00000179704) Formula: C52H85N4O12P (988.5901)	1.56 (100%)	Mus musculus [UBERON:0000956] cerebral cortex
MSI_000062962 Unavailable	989.5895	989.5895 ~ 989.5895 MzDiff: `none`	CL(8:0/8:0/8:0/14:0) (BioDeep_00000109153) Formula: C47H90O17P2 (988.5653)	-0.44 (100%)	Mus musculus [UBERON:0000956] cerebral cortex
MSI_000062974 Unavailable	989.5948	989.5948 ~ 989.5948 MzDiff: `none`	Not Annotated	-0.82 (0%)	Mus musculus [UBERON:0000956] cerebral cortex
MSI_000002550 Unreliable	989.5984	989.5984 ~ 989.5984 MzDiff: `none`	Not Annotated	0.45 (0%)	Rattus norvegicus [UBERON:0001950] neocortex
MSI_000002601 Unreliable	989.6034	989.6034 ~ 989.6034 MzDiff: `none`	hemicalyculin A (BioDeep_00000179704) Formula: C52H85N4O12P (988.5901)	0.13 (100%)	Rattus norvegicus [UBERON:0001950] neocortex
MSI_000002697 Unavailable	989.5915	989.5915 ~ 989.5915 MzDiff: `none`	n-[1-({1-[2-({1-[(1-{[3-(4-methoxyphenyl)-1-oxo-1-[2-(1,3-thiazol-2-yl)pyrrolidin-1-yl]propan-2-yl](methyl)carbamoyl}-2-methylpropyl)(methyl)carbamoyl]-2-methylpropyl}(methyl)carbamoyl)pyrrolidin-1-yl]-3-methyl-1-oxobutan-2-yl}(methyl)carbamoyl)ethyl]-n-methyloct-7-ynamide (BioDeep_00002085998) Formula: C53H80N8O8S (988.582)	-0.32 (100%)	Rattus norvegicus [UBERON:0001950] neocortex
MSI_000003055 Unreliable	989.6034	989.6034 ~ 989.6034 MzDiff: `none`	hemicalyculin A (BioDeep_00000179704) Formula: C52H85N4O12P (988.5901)	2.36 (100%)	Rattus norvegicus [UBERON:0002037] cerebellum
MSI_000003101 Unreliable	989.5984	989.5984 ~ 989.5984 MzDiff: `none`	Not Annotated	2.09 (0%)	Rattus norvegicus [UBERON:0002037] cerebellum
MSI_000003517 Unavailable	989.5915	989.5915 ~ 989.5915 MzDiff: `none`	n-[1-({1-[2-({1-[(1-{[3-(4-methoxyphenyl)-1-oxo-1-[2-(1,3-thiazol-2-yl)pyrrolidin-1-yl]propan-2-yl](methyl)carbamoyl}-2-methylpropyl)(methyl)carbamoyl]-2-methylpropyl}(methyl)carbamoyl)pyrrolidin-1-yl]-3-methyl-1-oxobutan-2-yl}(methyl)carbamoyl)ethyl]-n-methyloct-7-ynamide (BioDeep_00002085998) Formula: C53H80N8O8S (988.582)	-0.53 (100%)	Rattus norvegicus [UBERON:0002037] cerebellum
MSI_000004760 Unreliable	989.5915	989.5915 ~ 989.5915 MzDiff: `none`	n-[1-({1-[2-({1-[(1-{[3-(4-methoxyphenyl)-1-oxo-1-[2-(1,3-thiazol-2-yl)pyrrolidin-1-yl]propan-2-yl](methyl)carbamoyl}-2-methylpropyl)(methyl)carbamoyl]-2-methylpropyl}(methyl)carbamoyl)pyrrolidin-1-yl]-3-methyl-1-oxobutan-2-yl}(methyl)carbamoyl)ethyl]-n-methyloct-7-ynamide (BioDeep_00002085998) Formula: C53H80N8O8S (988.582)	2.22 (100%)	Rattus norvegicus [UBERON:0002298] brainstem
MSI_000005059 Unavailable	989.5984	989.5984 ~ 989.5984 MzDiff: `none`	Not Annotated	-0.46 (0%)	Rattus norvegicus [UBERON:0002298] brainstem
MSI_000005145 Unavailable	989.6034	989.6034 ~ 989.6034 MzDiff: `none`	hemicalyculin A (BioDeep_00000179704) Formula: C52H85N4O12P (988.5901)	-0.6 (100%)	Rattus norvegicus [UBERON:0002298] brainstem
MSI_000005776 Unavailable	989.5915	989.5915 ~ 989.5915 MzDiff: `none`	n-[1-({1-[2-({1-[(1-{[3-(4-methoxyphenyl)-1-oxo-1-[2-(1,3-thiazol-2-yl)pyrrolidin-1-yl]propan-2-yl](methyl)carbamoyl}-2-methylpropyl)(methyl)carbamoyl]-2-methylpropyl}(methyl)carbamoyl)pyrrolidin-1-yl]-3-methyl-1-oxobutan-2-yl}(methyl)carbamoyl)ethyl]-n-methyloct-7-ynamide (BioDeep_00002085998) Formula: C53H80N8O8S (988.582)	-0.63 (100%)	Rattus norvegicus [UBERON:0002435] striatum
MSI_000005798 Unavailable	989.6034	989.6034 ~ 989.6034 MzDiff: `none`	hemicalyculin A (BioDeep_00000179704) Formula: C52H85N4O12P (988.5901)	-0.66 (100%)	Rattus norvegicus [UBERON:0002435] striatum
MSI_000005989 Unavailable	989.5984	989.5984 ~ 989.5984 MzDiff: `none`	Not Annotated	-1.19 (0%)	Rattus norvegicus [UBERON:0002435] striatum
MSI_000058965 Unavailable	989.5887	989.5887 ~ 989.5887 MzDiff: `none`	CL(8:0/8:0/8:0/14:0) (BioDeep_00000109153) Formula: C47H90O17P2 (988.5653)	-0.59 (100%)	Mus musculus [UBERON:0001950] neocortex
MSI_000059360 Unreliable	989.5887	989.5887 ~ 989.5887 MzDiff: `none`	CL(8:0/8:0/8:0/14:0) (BioDeep_00000109153) Formula: C47H90O17P2 (988.5653)	1.15 (100%)	Mus musculus [UBERON:0002298] brainstem
MSI_000059870 Unavailable	989.6033	989.6033 ~ 989.6033 MzDiff: `none`	hemicalyculin A (BioDeep_00000179704) Formula: C52H85N4O12P (988.5901)	-0.66 (100%)	Mus musculus [UBERON:0002298] brainstem
MSI_000060788 Unavailable	989.6033	989.6033 ~ 989.6033 MzDiff: `none`	hemicalyculin A (BioDeep_00000179704) Formula: C52H85N4O12P (988.5901)	-0.49 (100%)	Mus musculus [UBERON:0002421] hippocampal formation
MSI_000060936 Unreliable	989.5879	989.5879 ~ 989.5879 MzDiff: `none`	CL(8:0/8:0/8:0/14:0) (BioDeep_00000109153) Formula: C47H90O17P2 (988.5653)	1.9 (100%)	Mus musculus [UBERON:0002421] hippocampal formation
MSI_000061855 Unavailable	989.5879	989.5879 ~ 989.5879 MzDiff: `none`	CL(8:0/8:0/8:0/14:0) (BioDeep_00000109153) Formula: C47H90O17P2 (988.5653)	-0.48 (100%)	Mus musculus [UBERON:0000956] cerebral cortex
MSI_000063027 Unreliable	989.5948	989.5948 ~ 989.5948 MzDiff: `none`	Not Annotated	2.04 (0%)	Mus musculus [UBERON:0002421] hippocampal formation
MSI_000063417 Unreliable	989.5906	989.5906 ~ 989.5906 MzDiff: `none`	CL(8:0/8:0/8:0/14:0) (BioDeep_00000109153) Formula: C47H90O17P2 (988.5653)	2.04 (100%)	Mus musculus [UBERON:0002421] hippocampal formation

Found 2 Sample Hits

Metabolite	Species	Sample
n-[1-({1-[2-({1-[(1-{[3-(4-methoxyphenyl)-1-oxo-1-[2-(1,3-thiazol-2-yl)pyrrolidin-1-yl]propan-2-yl](methyl)carbamoyl}-2-methylpropyl)(methyl)carbamoyl]-2-methylpropyl}(methyl)carbamoyl)pyrrolidin-1-yl]-3-methyl-1-oxobutan-2-yl}(methyl)carbamoyl)ethyl]-n-methyloct-7-ynamide Formula: C53H80N8O8S (988.582) Adducts: [M+H]+ (Ppm: 2.3)	Rattus norvegicus (Brain)	Spectroswiss - sol_2x_br_2 Resolution: 17μm, 488x193 Description
m/z_989.5948 Formula: - (n/a) Adducts: (Ppm: 0)	Mus musculus (brain)	Brain01_Bregma1-42_01_centroid Resolution: 17μm, 447x118 Description

Metabolite

Species

Sample

n-[1-({1-[2-({1-[(1-{[3-(4-methoxyphenyl)-1-oxo-1-[2-(1,3-thiazol-2-yl)pyrrolidin-1-yl]propan-2-yl](methyl)carbamoyl}-2-methylpropyl)(methyl)carbamoyl]-2-methylpropyl}(methyl)carbamoyl)pyrrolidin-1-yl]-3-methyl-1-oxobutan-2-yl}(methyl)carbamoyl)ethyl]-n-methyloct-7-ynamide

Formula: C53H80N8O8S (988.582)
Adducts: [M+H]+ (Ppm: 2.3)

Rattus norvegicus (Brain)

Spectroswiss - sol_2x_br_2

Resolution: 17μm, 488x193

Description

m/z_989.5948

Formula: - (n/a)
Adducts: (Ppm: 0)

Mus musculus (brain)

Brain01_Bregma1-42_01_centroid

Resolution: 17μm, 447x118

Description