M/Z: 832.6305
Hit 2 annotations: PA(22:5(4Z,7Z,10Z,13Z,16Z)/24:1(15Z))_[M-H2O+NH4]+; PA(a-25:0/18:1(12Z)-O(9S,10R))_[M+NH4]+
- Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
- Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
- Unreliable: 这个参考离子具有较高的排名价值，但缺乏可重复性。
- Unavailable: 由于排名价值低且缺乏可重复性，这个参考离子不应用于注释。
Found 5 Reference Ions Near m/z 832.6305
| NovoCell ID | m/z | Mass Window | Metabolite | Ranking | Anatomy Context |
|---|---|---|---|---|---|
| MSI_000043679 Reliable | 832.6237 | 832.6231 ~ 832.6239 MzDiff: 3.4 ppm |
PA(22:5(4Z,7Z,10Z,13Z,16Z)/24:1(15Z)) (BioDeep_00000107731) Formula: C49H85O8P (832.5982) |
4.42 (100%) | Homo sapiens [UBERON:0001043] esophagus |
| MSI_000065277 Reliable | 832.6215 | 832.6214 ~ 832.6216 MzDiff: 0.9 ppm |
PS(15:0/24:1(15Z)) (BioDeep_00000104703) Formula: C45H86NO10P (831.5989) |
4.06 (67%) | Homo sapiens [UBERON:0001155] colon |
| MSI_000047423 Unreliable | 832.6255 | 832.6255 ~ 832.6255 MzDiff: none |
PA(22:5(4Z,7Z,10Z,13Z,16Z)/24:1(15Z)) (BioDeep_00000107731) Formula: C49H85O8P (832.5982) |
2.3 (100%) | Homo sapiens [UBERON:0013067] colorectal mucosa |
| MSI_000052517 Unreliable | 832.6292 | 832.6292 ~ 832.6292 MzDiff: none |
Not Annotated | 1.85 (0%) | Homo sapiens [UBERON:0001052] rectum |
| MSI_000057923 Unreliable | 832.6231 | 832.6231 ~ 832.6231 MzDiff: none |
PA(22:5(4Z,7Z,10Z,13Z,16Z)/24:1(15Z)) (BioDeep_00000107731) Formula: C49H85O8P (832.5982) |
1.09 (100%) | Homo sapiens [UBERON:0007779] transudate |
Found 5 Sample Hits
| Metabolite | Species | Sample | |
|---|---|---|---|
| PA(22:5(4Z,7Z,10Z,13Z,16Z)/24:1(15Z)) Formula: C49H85O8P (832.5982) Adducts: [M-H2O+NH4]+ (Ppm: 16.3) |
Mus musculus (Lung) |
image1Resolution: 40μm, 187x165
Fig. 2 MALDI-MSI data from the same mouse lung tissue analyzed in Fig. 1. A: Optical image of the post-MSI, H&E-stained tissue section. B–D, F–G: Ion images of (B) m/z 796.6855 ([U13C-DPPC+Na]+), (C) m/z 756.5514 ([PC32:0+Na]+), (D) m/z 765.6079 ([D9-PC32:0+Na]+), (F) m/z 754.5359 ([PC32:1+Na]+), and (G) m/z 763.5923 ([D9-PC32:1+Na]+). E, H: Ratio images of (E) [D9-PC32:0+Na]+:[PC32:0+Na]+ and (H) [D9-PC32:1+Na]+:[PC32:1+Na]+. Part-per-million (ppm) mass errors are indicated in parentheses. All images were visualized using total-ion-current normalization and using hotspot removal (high quantile = 99%). DPPC = PC16:0/16:0. U13C-DPPC, universally 13C-labeled dipalmitoyl PC; PC, phosphatidylcholine; MSI, mass spectrometry imaging; H&E, hematoxylin and eosin.
Fig 1-3, Fig S1-S3, S5 |
|
| PA(22:5(4Z,7Z,10Z,13Z,16Z)/24:1(15Z)) Formula: C49H85O8P (832.5982) Adducts: [M-H2O+NH4]+ (Ppm: 4.9) |
Homo sapiens (colorectal adenocarcinoma) |
80TopL, 50TopR, 70BottomL, 60BottomR-profileResolution: 17μm, 137x136
The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024). |
|
| PA(a-25:0/18:1(12Z)-O(9S,10R)) Formula: C46H87O9P (814.6087) Adducts: [M+NH4]+ (Ppm: 14.5) |
Homo sapiens (colorectal adenocarcinoma) |
520TopL, 490TopR, 510BottomL, 500BottomR-profileResolution: 17μm, 147x131
The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024). |
|
| m/z_832.6292 Formula: - (n/a) Adducts: (Ppm: 0) |
Homo sapiens (colorectal adenocarcinoma) |
439TopL, 409TopR, 429BottomL, 419BottomR-profileResolution: 17μm, 157x136
The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024). |
|
| PA(22:5(4Z,7Z,10Z,13Z,16Z)/24:1(15Z)) Formula: C49H85O8P (832.5982) Adducts: [M-H2O+NH4]+ (Ppm: 2.2) |
Homo sapiens (esophagus) |
LNTO30_7_1Resolution: 75μm, 69x68
|
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