M/Z: 824.4952

Hit 5 annotations: Azaspiracid_[M+H-H2O]+; N-Formyl-nle-leu-phe-nle-tyr-lys_[M+H]+; PG(18:3(6Z,9Z,12Z)/20:4(6E,8Z,11Z,14Z)+=O(5))_[M+NH4]+; Acetyldigitoxin_[M+NH4]+; PS(16:0/22:6(5Z,7Z,10Z,13Z,16Z,19Z)-OH(4))_[M+H]+

在BioDeep NovoCell知识数据库中，参考离子总共被划分为4个级别。

Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
Unreliable: 这个参考离子具有较高的排名价值，但缺乏可重复性。
Unavailable: 由于排名价值低且缺乏可重复性，这个参考离子不应用于注释。

Found 7 Reference Ions Near m/z 824.4952

NovoCell ID	m/z	Mass Window	Metabolite	Ranking	Anatomy Context
MSI_000043364 Reliable	824.4993	824.499 ~ 824.4999 MzDiff: `3.4 ppm`	PS(16:0/22:6(5Z,7Z,10Z,13Z,16Z,19Z)-OH(4)) (BioDeep_00000206182) Formula: C44H74NO11P (823.4999)	9.4 (53%)	Homo sapiens [UBERON:0001043] esophagus
MSI_000047086 Unreliable	824.4959	824.4959 ~ 824.4959 MzDiff: `none`	N-Formyl-nle-leu-phe-nle-tyr-lys (BioDeep_00000175148) Formula: C43H65N7O9 (823.4844)	2.85 (100%)	Homo sapiens [UBERON:0013067] colorectal mucosa
MSI_000047112 Unreliable	824.4893	824.4893 ~ 824.4893 MzDiff: `none`	Not Annotated	2.78 (0%)	Homo sapiens [UBERON:0013067] colorectal mucosa
MSI_000047142 Unreliable	824.505	824.505 ~ 824.505 MzDiff: `none`	PS(16:0/22:6(5Z,7Z,10Z,13Z,16Z,19Z)-OH(4)) (BioDeep_00000206182) Formula: C44H74NO11P (823.4999)	2.71 (100%)	Homo sapiens [UBERON:0013067] colorectal mucosa
MSI_000052064 Unreliable	824.4875	824.4875 ~ 824.4875 MzDiff: `none`	Acetyldigitoxin (BioDeep_00000000723) Formula: C43H66O14 (806.4452)	2.34 (100%)	Homo sapiens [UBERON:0001052] rectum
MSI_000052165 Unreliable	824.5015	824.5015 ~ 824.5015 MzDiff: `none`	PS(16:0/22:6(5Z,7Z,10Z,13Z,16Z,19Z)-OH(4)) (BioDeep_00000206182) Formula: C44H74NO11P (823.4999)	2.29 (100%)	Homo sapiens [UBERON:0001052] rectum
MSI_000065402 Unreliable	824.4976	824.4975 ~ 824.4977 MzDiff: `1.0 ppm`	Azaspiracid (BioDeep_00000024395) Formula: C47H71NO12 (841.4976)	2.25 (100%)	Homo sapiens [UBERON:0001155] colon

Found 17 Sample Hits

Metabolite	Species	Sample
Azaspiracid Formula: C47H71NO12 (841.4976) Adducts: [M+H-H2O]+ (Ppm: 5.9)	Homo sapiens (esophagus)	LNTO22_1_3 Resolution: 75μm, 121x68 Description
N-Formyl-nle-leu-phe-nle-tyr-lys Formula: C43H65N7O9 (823.4844) Adducts: [M+H]+ (Ppm: 4.3)	Homo sapiens (esophagus)	LNTO22_1_4 Resolution: 17μm, 82x80 Description
PG(18:3(6Z,9Z,12Z)/20:4(6E,8Z,11Z,14Z)+=O(5)) Formula: C44H71O11P (806.4734) Adducts: [M+NH4]+ (Ppm: 8.9)	Homo sapiens (esophagus)	LNTO22_1_9 Resolution: 75μm, 89x74 Description
N-Formyl-nle-leu-phe-nle-tyr-lys Formula: C43H65N7O9 (823.4844) Adducts: [M+H]+ (Ppm: 5.2)	Homo sapiens (colorectal adenocarcinoma)	80TopL, 50TopR, 70BottomL, 60BottomR-profile Resolution: 17μm, 137x136 Description The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024).
Acetyldigitoxin Formula: C43H66O14 (806.4452) Adducts: [M+NH4]+ (Ppm: 18.7)	Homo sapiens (NA)	160TopL,130TopR,150BottomL,140BottomR-profile Resolution: 17μm, 142x136 Description
PS(16:0/22:6(5Z,7Z,10Z,13Z,16Z,19Z)-OH(4)) Formula: C44H74NO11P (823.4999) Adducts: [M+H]+ (Ppm: 9.6)	Homo sapiens (esophagus)	LNTO26_7_3 Resolution: 75μm, 82x88 Description
Azaspiracid Formula: C47H71NO12 (841.4976) Adducts: [M+H-H2O]+ (Ppm: 4.7)	Homo sapiens (esophagus)	TO31T Resolution: 75μm, 56x54 Description
Azaspiracid Formula: C47H71NO12 (841.4976) Adducts: [M+H-H2O]+ (Ppm: 5.7)	Homo sapiens (esophagus)	TO29T Resolution: 75μm, 56x48 Description
PS(16:0/22:6(5Z,7Z,10Z,13Z,16Z,19Z)-OH(4)) Formula: C44H74NO11P (823.4999) Adducts: [M+H]+ (Ppm: 9.3)	Homo sapiens (esophagus)	LNTO22_1_5 Resolution: 75μm, 135x94 Description
PS(16:0/22:6(5Z,7Z,10Z,13Z,16Z,19Z)-OH(4)) Formula: C44H74NO11P (823.4999) Adducts: [M+H]+ (Ppm: 10.1)	Homo sapiens (esophagus)	LNTO22_1_7 Resolution: 75μm, 69x54 Description
PS(16:0/22:6(5Z,7Z,10Z,13Z,16Z,19Z)-OH(4)) Formula: C44H74NO11P (823.4999) Adducts: [M+H]+ (Ppm: 9.8)	Homo sapiens (esophagus)	LNTO22_1_8 Resolution: 75μm, 69x61 Description
PS(16:0/22:6(5Z,7Z,10Z,13Z,16Z,19Z)-OH(4)) Formula: C44H74NO11P (823.4999) Adducts: [M+H]+ (Ppm: 9.7)	Homo sapiens (esophagus)	LNTO22_2_2 Resolution: 75μm, 135x94 Description
PS(16:0/22:6(5Z,7Z,10Z,13Z,16Z,19Z)-OH(4)) Formula: C44H74NO11P (823.4999) Adducts: [M+H]+ (Ppm: 10.2)	Homo sapiens (esophagus)	LNTO26_16_1 Resolution: 75μm, 95x88 Description
Azaspiracid Formula: C47H71NO12 (841.4976) Adducts: [M+H-H2O]+ (Ppm: 3.9)	Homo sapiens (colorectal adenocarcinoma)	240TopL, 210TopR, 230BottomL, 220BottomR-centroid Resolution: 50μm, 142x141 Description
Azaspiracid Formula: C47H71NO12 (841.4976) Adducts: [M+H-H2O]+ (Ppm: 4.8)	Homo sapiens (colorectal adenocarcinoma)	200TopL, 170TopR, 190BottomL, 180BottomR-centroid Resolution: 50μm, 132x126 Description
Azaspiracid Formula: C47H71NO12 (841.4976) Adducts: [M+H-H2O]+ (Ppm: 4.1)	Homo sapiens (colorectal adenocarcinoma)	160TopL,130TopR,150BottomL,140BottomR-centroid Resolution: 50μm, 142x136 Description
Azaspiracid Formula: C47H71NO12 (841.4976) Adducts: [M+H-H2O]+ (Ppm: 4.7)	Homo sapiens (colorectal adenocarcinoma)	120TopL, 90TopR, 110BottomL, 100BottomR-centroid Resolution: 50μm, 132x136 Description