M/Z: 685.5296

Hit 2 annotations: Trodusquemine_[M+H]+; Calcium ionophore_[M+H]+

在BioDeep NovoCell知识数据库中，参考离子总共被划分为4个级别。

Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
Unreliable: 这个参考离子具有较高的排名价值，但缺乏可重复性。
Unavailable: 由于排名价值低且缺乏可重复性，这个参考离子不应用于注释。

Found 6 Reference Ions Near m/z 685.5296

NovoCell ID	m/z	Mass Window	Metabolite	Ranking	Anatomy Context
MSI_000043054 Reliable	685.5286	685.528 ~ 685.5289 MzDiff: `3.4 ppm`	Trodusquemine (BioDeep_00000184592) Formula: C37H72N4O5S (684.5223)	5.65 (100%)	Homo sapiens [UBERON:0001043] esophagus
MSI_000056951 Unreliable	685.5284	685.528 ~ 685.5288 MzDiff: `3.1 ppm`	Trodusquemine (BioDeep_00000184592) Formula: C37H72N4O5S (684.5223)	3.09 (100%)	Homo sapiens [UBERON:0007779] transudate
MSI_000065403 Unreliable	685.5283	685.528 ~ 685.5285 MzDiff: `1.9 ppm`	Trodusquemine (BioDeep_00000184592) Formula: C37H72N4O5S (684.5223)	3.4 (100%)	Homo sapiens [UBERON:0001155] colon
MSI_000065722 Unreliable	685.526	685.526 ~ 685.526 MzDiff: `none`	Trodusquemine (BioDeep_00000184592) Formula: C37H72N4O5S (684.5223)	1.66 (100%)	Homo sapiens [UBERON:0001155] colon
MSI_000050238 Unreliable	685.5276	685.5276 ~ 685.5276 MzDiff: `none`	Trodusquemine (BioDeep_00000184592) Formula: C37H72N4O5S (684.5223)	0.31 (100%)	Mytilus edulis [UBERON:0009120] gill filament
MSI_000050543 Unreliable	685.5276	685.5276 ~ 685.5276 MzDiff: `none`	Trodusquemine (BioDeep_00000184592) Formula: C37H72N4O5S (684.5223)	2.13 (100%)	Mytilus edulis [UBERON:2001856] gill ray

Found 21 Sample Hits

Metabolite	Species	Sample
Trodusquemine Formula: C37H72N4O5S (684.5223) Adducts: [M+H]+ (Ppm: 1)	Homo sapiens (esophagus)	LNTO22_1_3 Resolution: 75μm, 121x68 Description
Trodusquemine Formula: C37H72N4O5S (684.5223) Adducts: [M+H]+ (Ppm: 1.2)	Homo sapiens (esophagus)	LNTO29_16_2 Resolution: 17μm, 95x101 Description
Trodusquemine Formula: C37H72N4O5S (684.5223) Adducts: [M+H]+ (Ppm: 2.3)	Homo sapiens (esophagus)	TO42T Resolution: 17μm, 69x81 Description
Trodusquemine Formula: C37H72N4O5S (684.5223) Adducts: [M+H]+ (Ppm: 5.1)	Homo sapiens (esophagus)	LNTO22_1_9 Resolution: 75μm, 89x74 Description
Calcium ionophore Formula: C38H72N2O8 (684.5288) Adducts: [M+H]+ (Ppm: 9.1)	Homo sapiens (colorectal adenocarcinoma)	80TopL, 50TopR, 70BottomL, 60BottomR-profile Resolution: 17μm, 137x136 Description The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024).
Trodusquemine Formula: C37H72N4O5S (684.5223) Adducts: [M+H]+ (Ppm: 2.9)	Mytilus edulis (gill)	20190202_MS38_Crassostrea_Gill_350-1500_DHB_pos_A25_11um_305x210 Resolution: 11μm, 305x210 Description single cell layer `class_4` is the gill structure cells, metabolite ion 534.2956 is the top representive ion of this type of cell
Calcium ionophore Formula: C38H72N2O8 (684.5288) Adducts: [M+H]+ (Ppm: 12)	Homo sapiens (colorectal adenocarcinoma)	520TopL, 490TopR, 510BottomL, 500BottomR-profile Resolution: 17μm, 147x131 Description The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024).
Calcium ionophore Formula: C38H72N2O8 (684.5288) Adducts: [M+H]+ (Ppm: 3.5)	Homo sapiens (colorectal adenocarcinoma)	439TopL, 409TopR, 429BottomL, 419BottomR-profile Resolution: 17μm, 157x136 Description The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024).
Trodusquemine Formula: C37H72N4O5S (684.5223) Adducts: [M+H]+ (Ppm: 1.7)	Homo sapiens (esophagus)	LNTO29_16_3 Resolution: 17μm, 108x107 Description
Trodusquemine Formula: C37H72N4O5S (684.5223) Adducts: [M+H]+ (Ppm: 0)	Homo sapiens (esophagus)	LNTO26_7_3 Resolution: 75μm, 82x88 Description
Trodusquemine Formula: C37H72N4O5S (684.5223) Adducts: [M+H]+ (Ppm: 1.7)	Homo sapiens (esophagus)	TO41T Resolution: 75μm, 69x43 Description
Trodusquemine Formula: C37H72N4O5S (684.5223) Adducts: [M+H]+ (Ppm: 0.5)	Homo sapiens (esophagus)	LNTO22_1_5 Resolution: 75μm, 135x94 Description
Trodusquemine Formula: C37H72N4O5S (684.5223) Adducts: [M+H]+ (Ppm: 3.2)	Homo sapiens (esophagus)	LNTO22_1_7 Resolution: 75μm, 69x54 Description
Trodusquemine Formula: C37H72N4O5S (684.5223) Adducts: [M+H]+ (Ppm: 1.3)	Homo sapiens (esophagus)	LNTO22_1_8 Resolution: 75μm, 69x61 Description
Trodusquemine Formula: C37H72N4O5S (684.5223) Adducts: [M+H]+ (Ppm: 1.2)	Homo sapiens (esophagus)	LNTO22_2_1 Resolution: 75μm, 89x88 Description
Trodusquemine Formula: C37H72N4O5S (684.5223) Adducts: [M+H]+ (Ppm: 0.3)	Homo sapiens (esophagus)	LNTO22_2_2 Resolution: 75μm, 135x94 Description
Trodusquemine Formula: C37H72N4O5S (684.5223) Adducts: [M+H]+ (Ppm: 1.6)	Homo sapiens (esophagus)	LNTO29_18_2 Resolution: 75μm, 62x68 Description
Trodusquemine Formula: C37H72N4O5S (684.5223) Adducts: [M+H]+ (Ppm: 2.3)	Homo sapiens (colorectal adenocarcinoma)	240TopL, 210TopR, 230BottomL, 220BottomR-centroid Resolution: 50μm, 142x141 Description
Trodusquemine Formula: C37H72N4O5S (684.5223) Adducts: [M+H]+ (Ppm: 5.2)	Homo sapiens (colorectal adenocarcinoma)	200TopL, 170TopR, 190BottomL, 180BottomR-centroid Resolution: 50μm, 132x126 Description
Trodusquemine Formula: C37H72N4O5S (684.5223) Adducts: [M+H]+ (Ppm: 1.6)	Homo sapiens (colorectal adenocarcinoma)	160TopL,130TopR,150BottomL,140BottomR-centroid Resolution: 50μm, 142x136 Description
Trodusquemine Formula: C37H72N4O5S (684.5223) Adducts: [M+H]+ (Ppm: 1.9)	Homo sapiens (colorectal adenocarcinoma)	120TopL, 90TopR, 110BottomL, 100BottomR-centroid Resolution: 50μm, 132x136 Description