M/Z: 659.0179


Hit 2 annotations:  dictazoline B_[M+Na]+; (1r,3s,9s,23s,34r)-23,34-dihydroxy-15,19-dimethoxy-30-methyl-6,10,17-trioxa-25,26,27,28-tetrathia-2,30-diazaheptacyclo[22.4.2.1¹,⁴.1²,²⁴.1¹²,¹⁶.1¹⁸,²².0³,⁹]tetratriaconta-4,7,12,14,16(33),18(32),19,21-octaene-11,29,31-trione_[M+H-H2O]+


在BioDeep NovoCell知识数据库中，参考离子总共被划分为4个级别。
  • Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
  • Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
  • Unreliable: 这个参考离子具有较高的排名价值，但缺乏可重复性。
  • Unavailable: 由于排名价值低且缺乏可重复性，这个参考离子不应用于注释。

Found 1 Reference Ions Near m/z 659.0179
NovoCell ID m/z Mass Window Metabolite Ranking Anatomy Context
MSI_000017170 Unavailable 659.0137 659.0137 ~ 659.0137
MzDiff: none		 dictazoline B (BioDeep_00000235546)
Formula: C26H22Br2N8O2 (636.0232)		 -0.34 (100%) Vitis vinifera
[PO:0009086] endocarp

Found 4 Sample Hits
Metabolite Species Sample
dictazoline B

Formula: C26H22Br2N8O2 (636.0232)
Adducts: [M+Na]+ (Ppm: 1.9) 		Vitis vinifera (Fruit)
grape_dhb_164_1
Resolution: 17μm, 136x122

Description

Grape berries fruit, condition: Late
(1r,3s,9s,23s,34r)-23,34-dihydroxy-15,19-dimethoxy-30-methyl-6,10,17-trioxa-25,26,27,28-tetrathia-2,30-diazaheptacyclo[22.4.2.1¹,⁴.1²,²⁴.1¹²,¹⁶.1¹⁸,²².0³,⁹]tetratriaconta-4,7,12,14,16(33),18(32),19,21-octaene-11,29,31-trione

Formula: C28H24N2O10S4 (676.0314)
Adducts: [M+H-H2O]+ (Ppm: 15.5) 		Mytilus edulis (mantle)
20190201_MS38_Crassostrea_Mantle_350-1500_DHB_pos_A28_10um_270x210
Resolution: 10μm, 270x210

Description

(1r,3s,9s,23s,34r)-23,34-dihydroxy-15,19-dimethoxy-30-methyl-6,10,17-trioxa-25,26,27,28-tetrathia-2,30-diazaheptacyclo[22.4.2.1¹,⁴.1²,²⁴.1¹²,¹⁶.1¹⁸,²².0³,⁹]tetratriaconta-4,7,12,14,16(33),18(32),19,21-octaene-11,29,31-trione

Formula: C28H24N2O10S4 (676.0314)
Adducts: [M+H-H2O]+ (Ppm: 16.4) 		Mytilus edulis (gill)
20190202_MS38_Crassostrea_Gill_350-1500_DHB_pos_A25_11um_305x210
Resolution: 11μm, 305x210

Description

single cell layer class_4 is the gill structure cells, metabolite ion 534.2956 is the top representive ion of this type of cell
(1r,3s,9s,23s,34r)-23,34-dihydroxy-15,19-dimethoxy-30-methyl-6,10,17-trioxa-25,26,27,28-tetrathia-2,30-diazaheptacyclo[22.4.2.1¹,⁴.1²,²⁴.1¹²,¹⁶.1¹⁸,²².0³,⁹]tetratriaconta-4,7,12,14,16(33),18(32),19,21-octaene-11,29,31-trione

Formula: C28H24N2O10S4 (676.0314)
Adducts: [M+H-H2O]+ (Ppm: 16.4) 		Mytilus edulis (mantle)
20190216_MS38_Mytilus_mantle_350-1500_DHB_pos_A26_10um_275x210
Resolution: 10μm, 275x210

Description