M/Z: 625.0976

Hit 2 annotations: Afoxolaner_[M-H2O+NH4]+; [(2r,3s,4s,5r,6s)-3,4,5-trihydroxy-6-{[(1z)-5-methanesulfinyl-1-(sulfoimino)pent-4-en-1-yl]sulfanyl}oxan-2-yl]methyl (2e)-3-(4-hydroxy-3,5-dimethoxyphenyl)prop-2-enoate_[M]+

在BioDeep NovoCell知识数据库中，参考离子总共被划分为4个级别。

Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
Unreliable: 这个参考离子具有较高的排名价值，但缺乏可重复性。
Unavailable: 由于排名价值低且缺乏可重复性，这个参考离子不应用于注释。

Found 2 Reference Ions Near m/z 625.0976

NovoCell ID	m/z	Mass Window	Metabolite	Ranking	Anatomy Context
MSI_000054855 Unreliable	625.0976	625.0976 ~ 625.0976 MzDiff: `none`	Afoxolaner (BioDeep_00000175774) Formula: C26H17ClF9N3O3 (625.0815)	1.69 (100%)	MALDI - DHB [NOVOCELL:BACKGROUND] blank
MSI_000024555 Unreliable	625.0958	625.0958 ~ 625.0958 MzDiff: `none`	Afoxolaner (BioDeep_00000175774) Formula: C26H17ClF9N3O3 (625.0815)	1.78 (100%)	Mus musculus [UBERON:0004269] upper arm connective tissue

Found 8 Sample Hits

Metabolite	Species	Sample
Afoxolaner Formula: C26H17ClF9N3O3 (625.0815) Adducts: [M-H2O+NH4]+ (Ppm: 12.4)	Homo sapiens (Liver)	20171107_FIT4_DHBpos_p70_s50 Resolution: 50μm, 70x70 Description
Afoxolaner Formula: C26H17ClF9N3O3 (625.0815) Adducts: [M-H2O+NH4]+ (Ppm: 14.3)	Mus musculus (Left upper arm)	357_l_total ion count Resolution: 50μm, 97x131 Description Diseased
[(2r,3s,4s,5r,6s)-3,4,5-trihydroxy-6-{[(1z)-5-methanesulfinyl-1-(sulfoimino)pent-4-en-1-yl]sulfanyl}oxan-2-yl]methyl (2e)-3-(4-hydroxy-3,5-dimethoxyphenyl)prop-2-enoate Formula: C23H31NO13S3 (625.0957) Adducts: [M]+ (Ppm: 5)	Posidonia oceanica (root)	20190613_MS1_A19r-18 Resolution: 17μm, 246x264 Description
[(2r,3s,4s,5r,6s)-3,4,5-trihydroxy-6-{[(1z)-5-methanesulfinyl-1-(sulfoimino)pent-4-en-1-yl]sulfanyl}oxan-2-yl]methyl (2e)-3-(4-hydroxy-3,5-dimethoxyphenyl)prop-2-enoate Formula: C23H31NO13S3 (625.0957) Adducts: [M]+ (Ppm: 3.8)	Posidonia oceanica (root)	MS1_20180404_PO_1200 Resolution: 17μm, 193x208 Description
Afoxolaner Formula: C26H17ClF9N3O3 (625.0815) Adducts: [M-H2O+NH4]+ (Ppm: 11.4)	Mytilus edulis (mantle)	20190201_MS38_Crassostrea_Mantle_350-1500_DHB_pos_A28_10um_270x210 Resolution: 10μm, 270x210 Description
Afoxolaner Formula: C26H17ClF9N3O3 (625.0815) Adducts: [M-H2O+NH4]+ (Ppm: 13)	Mytilus edulis (gill)	20190202_MS38_Crassostrea_Gill_350-1500_DHB_pos_A25_11um_305x210 Resolution: 11μm, 305x210 Description single cell layer `class_4` is the gill structure cells, metabolite ion 534.2956 is the top representive ion of this type of cell
Afoxolaner Formula: C26H17ClF9N3O3 (625.0815) Adducts: [M-H2O+NH4]+ (Ppm: 12.2)	Mytilus edulis (mantle)	20190216_MS38_Mytilus_mantle_350-1500_DHB_pos_A26_10um_275x210 Resolution: 10μm, 275x210 Description
m/z_625.0975 Formula: - (n/a) Adducts: (Ppm: 0)	Drosophila melanogaster (brain)	Drosophila18 Resolution: 5μm, 686x685 Description Sample information Organism: Drosophila melanogaster Organism part: Brain Condition: Healthy Sample preparation Sample stabilisation: Frozen Tissue modification: Frozen MALDI matrix: 2,5-dihydroxybenzoic acid (DHB) MALDI matrix application: TM sprayer Solvent: Aceton/water MS analysis Polarity: Positive Ionisation source: Prototype Analyzer: Orbitrap Pixel size: 5μm × 5μm Annotation settings m/z tolerance (ppm): 3 Analysis version: Original MSM Pixel count: 469910 Imzml file size: 696.23 MB Ibd file size: 814.11 MB