M/Z: 624.2362

Hit 3 annotations: (1s,2r,3as,5r,7s,7ar)-2-[(2e)-but-2-enoyl]-1-{[(1s,5s,6s)-4'-chloro-1-hexyl-2-hydroxy-2',4,5'-trioxo-3'-[(1e)-prop-1-en-1-yl]-3-azaspiro[bicyclo[3.1.0]hexane-6,1'-cyclopentane]-2,3'-dien-5-yl]carbonyl}-2-hydroxy-7-methyl-octahydroindene-5-carboxylic acid_[M+H-H2O]+; 1,5-Bis(4'-glucopyranosyloxy-3'-hydroxyphenyl)pent-4-en-1-yne_[M+NH4]+; 1-{4-[5-(7-hydroxy-6-methoxy-3,4-dihydroisoquinoline-1-carbonyl)-2-methoxyphenoxy]benzoyl}-6-methoxy-3,4-dihydroisoquinolin-7-ol_[M+NH4]+

在BioDeep NovoCell知识数据库中，参考离子总共被划分为4个级别。

Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
Unreliable: 这个参考离子具有较高的排名价值，但缺乏可重复性。
Unavailable: 由于排名价值低且缺乏可重复性，这个参考离子不应用于注释。

Found 1 Reference Ions Near m/z 624.2362

NovoCell ID	m/z	Mass Window	Metabolite	Ranking	Anatomy Context
MSI_000029951 Unavailable	624.2356	624.2356 ~ 624.2356 MzDiff: `none`	1,5-Bis(4'-glucopyranosyloxy-3'-hydroxyphenyl)pent-4-en-1-yne (BioDeep_00000175309) Formula: C29H34O14 (606.1948)	-0.37 (100%)	Macropus giganteus [UBERON:0002336] corpus callosum

Found 3 Sample Hits

Metabolite Species Sample

Metabolite	Species	Sample
(1s,2r,3as,5r,7s,7ar)-2-[(2e)-but-2-enoyl]-1-{[(1s,5s,6s)-4'-chloro-1-hexyl-2-hydroxy-2',4,5'-trioxo-3'-[(1e)-prop-1-en-1-yl]-3-azaspiro[bicyclo[3.1.0]hexane-6,1'-cyclopentane]-2,3'-dien-5-yl]carbonyl}-2-hydroxy-7-methyl-octahydroindene-5-carboxylic acid Formula: C34H40ClNO9 (641.2391) Adducts: [M+H-H2O]+ (Ppm: 2)	Marker Pen (NA)	3ul_0.8Mpa_RAW_20241016-PAPER PNMK Resolution: 30μm, 315x42 Description By writing the four English letters “PNMK” on white paper with a marker pen, and then scanning with a DESI ion source to obtain the scanning result. The signal of the chemical substances on the marker pen used appears on the channel with an m/z value of `322.1918`, `323.1953`, `546.4010`, and etc, from the single cell deconvolution sampling layer `class_4`. This test data was tested by chuxiaoping from PANOMIX’s R&D laboratory.
1,5-Bis(4'-glucopyranosyloxy-3'-hydroxyphenyl)pent-4-en-1-yne Formula: C29H34O14 (606.1948) Adducts: [M+NH4]+ (Ppm: 11.1)	Macropus giganteus (Brain)	170321_kangaroobrain-dan3-pos_maxof50.0_med1 Resolution: 50μm, 81x50 Description Sample information Organism: Macropus giganteus (kangaroo) Organism part: Brain Condition: Wildtype Sample growth conditions: Wild
1-{4-[5-(7-hydroxy-6-methoxy-3,4-dihydroisoquinoline-1-carbonyl)-2-methoxyphenoxy]benzoyl}-6-methoxy-3,4-dihydroisoquinolin-7-ol Formula: C35H30N2O8 (606.2002) Adducts: [M+NH4]+ (Ppm: 3.5)	Posidonia oceanica (root)	20190828_MS1_A19r-22 Resolution: 17μm, 292x279 Description

(1s,2r,3as,5r,7s,7ar)-2-[(2e)-but-2-enoyl]-1-{[(1s,5s,6s)-4'-chloro-1-hexyl-2-hydroxy-2',4,5'-trioxo-3'-[(1e)-prop-1-en-1-yl]-3-azaspiro[bicyclo[3.1.0]hexane-6,1'-cyclopentane]-2,3'-dien-5-yl]carbonyl}-2-hydroxy-7-methyl-octahydroindene-5-carboxylic acid

Formula: C34H40ClNO9 (641.2391)
Adducts: [M+H-H2O]+ (Ppm: 2)

Marker Pen (NA)

3ul_0.8Mpa_RAW_20241016-PAPER PNMK

Resolution: 30μm, 315x42

Description

By writing the four English letters “PNMK” on white paper with a marker pen, and then scanning with a DESI ion source to obtain the scanning result. The signal of the chemical substances on the marker pen used appears on the channel with an m/z value of 322.1918, 323.1953, 546.4010, and etc, from the single cell deconvolution sampling layer class_4. This test data was tested by chuxiaoping from PANOMIX’s R&D laboratory.

1,5-Bis(4'-glucopyranosyloxy-3'-hydroxyphenyl)pent-4-en-1-yne

Formula: C29H34O14 (606.1948)
Adducts: [M+NH4]+ (Ppm: 11.1)

Macropus giganteus (Brain)

170321_kangaroobrain-dan3-pos_maxof50.0_med1

Resolution: 50μm, 81x50

Description

Sample information Organism: Macropus giganteus (kangaroo) Organism part: Brain Condition: Wildtype Sample growth conditions: Wild

1-{4-[5-(7-hydroxy-6-methoxy-3,4-dihydroisoquinoline-1-carbonyl)-2-methoxyphenoxy]benzoyl}-6-methoxy-3,4-dihydroisoquinolin-7-ol

Formula: C35H30N2O8 (606.2002)
Adducts: [M+NH4]+ (Ppm: 3.5)

Posidonia oceanica (root)

20190828_MS1_A19r-22

Resolution: 17μm, 292x279

Description