M/Z: 593.329

Hit 3 annotations: Mesobilirubinogen_[M+H]+; (3as,3br,5ar,9as,9br,11ar)-7-[(3,5-dihydroxy-4-methoxy-6-methyloxan-2-yl)oxy]-3a-hydroxy-9a,11a-dimethyl-1-(5-oxo-2h-furan-3-yl)-tetradecahydrocyclopenta[a]phenanthren-2-yl acetate_[M+H]+; N-(N-(N-((Hexahydro-1H-azepin-1-yl)carbonyl)-L-leucyl)-D-tryptophyl)-D-tryptophan_[M+H-2H2O]+

在BioDeep NovoCell知识数据库中，参考离子总共被划分为4个级别。

Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
Unreliable: 这个参考离子具有较高的排名价值，但缺乏可重复性。
Unavailable: 由于排名价值低且缺乏可重复性，这个参考离子不应用于注释。

Found 4 Reference Ions Near m/z 593.329

NovoCell ID	m/z	Mass Window	Metabolite	Ranking	Anatomy Context
MSI_000006597 Reliable	593.3339	593.3338 ~ 593.334 MzDiff: `0.8 ppm`	N-(N-(N-((Hexahydro-1H-azepin-1-yl)carbonyl)-L-leucyl)-D-tryptophyl)-D-tryptophan (BioDeep_00000172820) Formula: C35H44N6O5 (628.3373)	5.56 (100%)	Rattus norvegicus [UBERON:0004358] caput epididymis
MSI_000017914 Unreliable	593.33	593.33 ~ 593.33 MzDiff: `none`	(3as,3br,5ar,9as,9br,11ar)-7-[(3,5-dihydroxy-4-methoxy-6-methyloxan-2-yl)oxy]-3a-hydroxy-9a,11a-dimethyl-1-(5-oxo-2h-furan-3-yl)-tetradecahydrocyclopenta[a]phenanthren-2-yl acetate (BioDeep_00002072764) Formula: C32H48O10 (592.3247)	0.24 (100%)	Vitis vinifera [PO:0009087] mesocarp
MSI_000004062 Unreliable	593.329	593.329 ~ 593.329 MzDiff: `none`	Mesobilirubinogen (BioDeep_00000003497) Formula: C33H44N4O6 (592.3261)	1.09 (100%)	Homo sapiens [UBERON:0002107] liver
MSI_000016388 Unreliable	593.33	593.33 ~ 593.33 MzDiff: `none`	(3as,3br,5ar,9as,9br,11ar)-7-[(3,5-dihydroxy-4-methoxy-6-methyloxan-2-yl)oxy]-3a-hydroxy-9a,11a-dimethyl-1-(5-oxo-2h-furan-3-yl)-tetradecahydrocyclopenta[a]phenanthren-2-yl acetate (BioDeep_00002072764) Formula: C32H48O10 (592.3247)	0.9 (100%)	Vitis vinifera [PO:0009086] endocarp

Found 8 Sample Hits

Metabolite	Species	Sample
Mesobilirubinogen Formula: C33H44N4O6 (592.3261) Adducts: [M+H]+ (Ppm: 7.3)	Homo sapiens (Liver)	20171107_FIT4_DHBpos_p70_s50 Resolution: 50μm, 70x70 Description
(3as,3br,5ar,9as,9br,11ar)-7-[(3,5-dihydroxy-4-methoxy-6-methyloxan-2-yl)oxy]-3a-hydroxy-9a,11a-dimethyl-1-(5-oxo-2h-furan-3-yl)-tetradecahydrocyclopenta[a]phenanthren-2-yl acetate Formula: C32H48O10 (592.3247) Adducts: [M+H]+ (Ppm: 3.4)	Vitis vinifera (Fruit)	grape_dhb_91_1 Resolution: 50μm, 120x114 Description Grape berries fruit, condition: Ripe
(3as,3br,5ar,9as,9br,11ar)-7-[(3,5-dihydroxy-4-methoxy-6-methyloxan-2-yl)oxy]-3a-hydroxy-9a,11a-dimethyl-1-(5-oxo-2h-furan-3-yl)-tetradecahydrocyclopenta[a]phenanthren-2-yl acetate Formula: C32H48O10 (592.3247) Adducts: [M+H]+ (Ppm: 3.4)	Vitis vinifera (Fruit)	grape_dhb_164_1 Resolution: 17μm, 136x122 Description Grape berries fruit, condition: Late
(3as,3br,5ar,9as,9br,11ar)-7-[(3,5-dihydroxy-4-methoxy-6-methyloxan-2-yl)oxy]-3a-hydroxy-9a,11a-dimethyl-1-(5-oxo-2h-furan-3-yl)-tetradecahydrocyclopenta[a]phenanthren-2-yl acetate Formula: C32H48O10 (592.3247) Adducts: [M+H]+ (Ppm: 3.4)	Vitis vinifera (Fruit)	grape_dhb_163_1 Resolution: 17μm, 132x115 Description Grape berries fruit, condition: Late
N-(N-(N-((Hexahydro-1H-azepin-1-yl)carbonyl)-L-leucyl)-D-tryptophyl)-D-tryptophan Formula: C35H44N6O5 (628.3373) Adducts: [M+H-2H2O]+ (Ppm: 16.4)	Rattus norvegicus (Epididymis)	epik_dhb_head_ito01_04 Resolution: 17μm, 178x91 Description
N-(N-(N-((Hexahydro-1H-azepin-1-yl)carbonyl)-L-leucyl)-D-tryptophyl)-D-tryptophan Formula: C35H44N6O5 (628.3373) Adducts: [M+H-2H2O]+ (Ppm: 16.3)	Rattus norvegicus (Epididymis)	epik_dhb_head_ito01_03 Resolution: 17μm, 159x110 Description
N-(N-(N-((Hexahydro-1H-azepin-1-yl)carbonyl)-L-leucyl)-D-tryptophyl)-D-tryptophan Formula: C35H44N6O5 (628.3373) Adducts: [M+H-2H2O]+ (Ppm: 16.6)	Rattus norvegicus (Epididymis)	epik_dhb_head_ito01_06 Resolution: 17μm, 183x103 Description
N-(N-(N-((Hexahydro-1H-azepin-1-yl)carbonyl)-L-leucyl)-D-tryptophyl)-D-tryptophan Formula: C35H44N6O5 (628.3373) Adducts: [M+H-2H2O]+ (Ppm: 16.9)	Rattus norvegicus (Epididymis)	epik_dhb_head_ito03_14 Resolution: 17μm, 205x103 Description