M/Z: 593.1237

Hit 3 annotations: Prodelphinidin B_[M+H-H2O]+; Protoleucomelone_[M+H]+; 2-(3,4-dihydroxyphenyl)-8-[2-(3,4-dihydroxyphenyl)-3,5,7-trihydroxy-3,4-dihydro-2h-1-benzopyran-4-yl]-3,5,7-trihydroxy-2,3-dihydro-1-benzopyran-4-one_[M+H]+

在BioDeep NovoCell知识数据库中，参考离子总共被划分为4个级别。

Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
Unreliable: 这个参考离子具有较高的排名价值，但缺乏可重复性。
Unavailable: 由于排名价值低且缺乏可重复性，这个参考离子不应用于注释。

Found 3 Reference Ions Near m/z 593.1237

NovoCell ID	m/z	Mass Window	Metabolite	Ranking	Anatomy Context
MSI_000024549 Unreliable	593.1253	593.1253 ~ 593.1253 MzDiff: `none`	Prodelphinidin B (BioDeep_00000007951) Formula: C30H26O14 (610.1322)	1.78 (100%)	Mus musculus [UBERON:0004269] upper arm connective tissue
MSI_000027399 Unreliable	593.1197	593.1197 ~ 593.1197 MzDiff: `none`	Protoleucomelone (BioDeep_00000023921) Formula: C30H24O13 (592.1217)	2.01 (100%)	Mus musculus [UBERON:0000913] interstitial fluid
MSI_000038286 Unreliable	593.1257	593.1257 ~ 593.1257 MzDiff: `none`	2-(3,4-dihydroxyphenyl)-8-[2-(3,4-dihydroxyphenyl)-3,5,7-trihydroxy-3,4-dihydro-2h-1-benzopyran-4-yl]-3,5,7-trihydroxy-2,3-dihydro-1-benzopyran-4-one (BioDeep_00002062856) Formula: C30H24O13 (592.1217)	1.49 (100%)	Posidonia oceanica [PO:0005020] vascular bundle

Found 6 Sample Hits

Metabolite	Species	Sample
Prodelphinidin B Formula: C30H26O14 (610.1322) Adducts: [M+H-H2O]+ (Ppm: 7.9)	Homo sapiens (Liver)	20171107_FIT4_DHBpos_p70_s50 Resolution: 50μm, 70x70 Description
Prodelphinidin B Formula: C30H26O14 (610.1322) Adducts: [M+H-H2O]+ (Ppm: 8.9)	Mus musculus (Lung)	image1 Resolution: 40μm, 187x165 Description Fig. 2 MALDI-MSI data from the same mouse lung tissue analyzed in Fig. 1. A: Optical image of the post-MSI, H&E-stained tissue section. B–D, F–G: Ion images of (B) m/z 796.6855 ([U13C-DPPC+Na]+), (C) m/z 756.5514 ([PC32:0+Na]+), (D) m/z 765.6079 ([D9-PC32:0+Na]+), (F) m/z 754.5359 ([PC32:1+Na]+), and (G) m/z 763.5923 ([D9-PC32:1+Na]+). E, H: Ratio images of (E) [D9-PC32:0+Na]+:[PC32:0+Na]+ and (H) [D9-PC32:1+Na]+:[PC32:1+Na]+. Part-per-million (ppm) mass errors are indicated in parentheses. All images were visualized using total-ion-current normalization and using hotspot removal (high quantile = 99%). DPPC = PC16:0/16:0. U13C-DPPC, universally 13C-labeled dipalmitoyl PC; PC, phosphatidylcholine; MSI, mass spectrometry imaging; H&E, hematoxylin and eosin. Fig 1-3, Fig S1-S3, S5
Prodelphinidin B Formula: C30H26O14 (610.1322) Adducts: [M+H-H2O]+ (Ppm: 6.2)	Mus musculus (Left upper arm)	357_l_total ion count Resolution: 50μm, 97x131 Description Diseased
Protoleucomelone Formula: C30H24O13 (592.1217) Adducts: [M+H]+ (Ppm: 15.6)	Mus musculus (Lung)	image2 Resolution: 40μm, 550x256 Description Supplementary Figure S6. Ion distribution images for (a) [PC36:4+Na]+ (m/z 804.5514) and (b) [PC38:6+Na]+ (m/z 828.5515) obtained from mouse lung tissue collected 6 h after administration of D9- choline and U13C-DPPC–containing CHF5633. Parts-per-million (ppm) mass errors are indicated in parentheses. (c) Magnification of the boxed region in (a) with selected bronchiolar regions outlined in white boxes. (d) The corresponding H&E-stained tissue section with the same selected bronchiolar regions outlined in black boxes. These data demonstrate the co-localisation of the polyunsaturated lipids PC36:4 and PC38:6 with the bronchiolar regions of the lung. All MSI images were visualised using total ion current normalisation and hotspot removal (high quantile = 99%).
2-(3,4-dihydroxyphenyl)-8-[2-(3,4-dihydroxyphenyl)-3,5,7-trihydroxy-3,4-dihydro-2h-1-benzopyran-4-yl]-3,5,7-trihydroxy-2,3-dihydro-1-benzopyran-4-one Formula: C30H24O13 (592.1217) Adducts: [M+H]+ (Ppm: 5.5)	Posidonia oceanica (root)	20190613_MS1_A19r-18 Resolution: 17μm, 246x264 Description
Prodelphinidin B Formula: C30H26O14 (610.1322) Adducts: [M+H-H2O]+ (Ppm: 6.5)	Drosophila melanogaster (brain)	Drosophila18 Resolution: 5μm, 686x685 Description Sample information Organism: Drosophila melanogaster Organism part: Brain Condition: Healthy Sample preparation Sample stabilisation: Frozen Tissue modification: Frozen MALDI matrix: 2,5-dihydroxybenzoic acid (DHB) MALDI matrix application: TM sprayer Solvent: Aceton/water MS analysis Polarity: Positive Ionisation source: Prototype Analyzer: Orbitrap Pixel size: 5μm × 5μm Annotation settings m/z tolerance (ppm): 3 Analysis version: Original MSM Pixel count: 469910 Imzml file size: 696.23 MB Ibd file size: 814.11 MB