M/Z: 582.1053

Hit 0 annotations:

在BioDeep NovoCell知识数据库中，参考离子总共被划分为4个级别。

Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
Unreliable: 这个参考离子具有较高的排名价值，但缺乏可重复性。
Unavailable: 由于排名价值低且缺乏可重复性，这个参考离子不应用于注释。

Found 11 Reference Ions Near m/z 582.1053

NovoCell ID	m/z	Mass Window	Metabolite	Ranking	Anatomy Context
MSI_000011222 Unreliable	582.0984	582.0984 ~ 582.0984 MzDiff: `none`	Telomestatin (BioDeep_00000009055) Formula: C26H14N8O7S (582.0706)	1.75 (100%)	Mus musculus [UBERON:0012378] muscle layer of urinary bladder
MSI_000011108 Unreliable	582.1053	582.1053 ~ 582.1053 MzDiff: `none`	Not Annotated	2.09 (%)	Mus musculus [UBERON:0012378] muscle layer of urinary bladder
MSI_000011260 Unreliable	582.1127	582.1127 ~ 582.1127 MzDiff: `none`	dTDP-D-glucose (BioDeep_00000004493) Formula: C16H26N2O16P2 (564.0758)	1.6 (100%)	Mus musculus [UBERON:0012378] muscle layer of urinary bladder
MSI_000054119 Unreliable	582.1151	582.115 ~ 582.1153 MzDiff: `0.9 ppm`	{6-[cyano(phenyl)methoxy]-4,5-dihydroxy-3-(3,4,5-trihydroxybenzoyloxy)oxan-2-yl}methyl 3,4,5-trihydroxybenzoate (BioDeep_00002079008) Formula: C28H25NO14 (599.1275)	3.38 (100%)	MALDI - CHCA [NOVOCELL:BACKGROUND] blank
MSI_000009502 Unavailable	582.0984	582.0984 ~ 582.0984 MzDiff: `none`	Telomestatin (BioDeep_00000009055) Formula: C26H14N8O7S (582.0706)	-0.62 (100%)	Mus musculus [UBERON:0004645] urinary bladder urothelium
MSI_000009346 Unavailable	582.1053	582.1053 ~ 582.1053 MzDiff: `none`	Not Annotated	-0.1 (%)	Mus musculus [UBERON:0004645] urinary bladder urothelium
MSI_000009412 Unavailable	582.1127	582.1127 ~ 582.1127 MzDiff: `none`	dTDP-D-glucose (BioDeep_00000004493) Formula: C16H26N2O16P2 (564.0758)	-0.36 (100%)	Mus musculus [UBERON:0004645] urinary bladder urothelium
MSI_000000782 Unavailable	582.0984	582.0984 ~ 582.0984 MzDiff: `none`	Telomestatin (BioDeep_00000009055) Formula: C26H14N8O7S (582.0706)	-0.6 (100%)	Mus musculus [CL:0000066] epithelial cell
MSI_000000871 Unavailable	582.1127	582.1127 ~ 582.1127 MzDiff: `none`	dTDP-D-glucose (BioDeep_00000004493) Formula: C16H26N2O16P2 (564.0758)	-0.68 (100%)	Mus musculus [CL:0000066] epithelial cell
MSI_000033386 Unreliable	582.1143	582.1143 ~ 582.1143 MzDiff: `none`	{6-[cyano(phenyl)methoxy]-4,5-dihydroxy-3-(3,4,5-trihydroxybenzoyloxy)oxan-2-yl}methyl 3,4,5-trihydroxybenzoate (BioDeep_00002079008) Formula: C28H25NO14 (599.1275)	2.15 (100%)	Posidonia oceanica [PO:0005352] xylem
MSI_000040168 Unavailable	582.115	582.115 ~ 582.115 MzDiff: `none`	{6-[cyano(phenyl)methoxy]-4,5-dihydroxy-3-(3,4,5-trihydroxybenzoyloxy)oxan-2-yl}methyl 3,4,5-trihydroxybenzoate (BioDeep_00002079008) Formula: C28H25NO14 (599.1275)	-0.04 (100%)	Posidonia oceanica [PO:0005417] phloem

Found 1 Sample Hits

Metabolite	Species	Sample
m/z_582.1053 Formula: - (n/a) Adducts: (Ppm: )	Mus musculus (Urinary bladder)	HR2MSI_mouse_urinary_bladder - S096 Resolution: 10μm, 260x134 Description Mass spectrometry imaging of phospholipids in mouse urinary bladder (imzML dataset) The spatial distribution of phospholipids in a tissue section of mouse urinary bladder was analyzed by MALDI MS imaging at 10 micrometer pixel size with high mass resolution (using an LTQ Orbitrap mass spectrometer). R, ö, mpp A, Guenther S, Schober Y, Schulz O, Takats Z, Kummer W, Spengler B, Histology by mass spectrometry: label-free tissue characterization obtained from high-accuracy bioanalytical imaging. Angew Chem Int Ed Engl, 49(22):3834-8(2010) Fig. S2: Single ion images of compounds shown in Fig. 1A-B : (upper left to lower right) m/z = 743.5482 (unknown), m/z = 741.5307 (SM (16:0), [M+K]+), m/z = 798.5410 (PC (34:1), [M+K]+), m/z = 616.1767 (heme b, M+), m/z = 772.5253 (PC (32:0), [M+K]+). Stability of determined mass values was in the range of +/- 1 ppm over 22 hours of measurement (Fig. S4), with a standard deviation of 0.56 ppm. Accuracy data were obtained during tissue scanning experiments by monitoring the mass signal at nominal mass 798. The internal lock mass function of the Orbitrap instrument was used for automatic calibration during imaging measurements, using the known matrix-related ion signals at m/z = 137.0233, m/z = 444.0925 and m/z = 716.1246.

Metabolite

Species

Sample

m/z_582.1053

Formula: - (n/a)
Adducts: (Ppm: )

Mus musculus (Urinary bladder)

HR2MSI_mouse_urinary_bladder - S096

Resolution: 10μm, 260x134

Description

Mass spectrometry imaging of phospholipids in mouse urinary bladder (imzML dataset)
The spatial distribution of phospholipids in a tissue section of mouse urinary bladder was analyzed by MALDI MS imaging at 10 micrometer pixel size with high mass resolution (using an LTQ Orbitrap mass spectrometer).

R, ö, mpp A, Guenther S, Schober Y, Schulz O, Takats Z, Kummer W, Spengler B, Histology by mass spectrometry: label-free tissue characterization obtained from high-accuracy bioanalytical imaging. Angew Chem Int Ed Engl, 49(22):3834-8(2010)

Fig. S2: Single ion images of compounds shown in Fig. 1A-B : (upper left to lower right) m/z = 743.5482 (unknown), m/z = 741.5307 (SM (16:0), [M+K]+), m/z = 798.5410 (PC (34:1), [M+K]+), m/z = 616.1767 (heme b, M+), m/z = 772.5253 (PC (32:0), [M+K]+).

Stability of determined mass values was in the range of +/- 1 ppm over 22 hours of measurement (Fig. S4), with a standard deviation of 0.56 ppm. Accuracy data were obtained during tissue scanning experiments by monitoring the mass signal at nominal mass 798. The internal lock mass function of the Orbitrap instrument was used for automatic calibration during imaging measurements, using the known matrix-related ion signals at m/z = 137.0233, m/z = 444.0925 and m/z = 716.1246.