M/Z: 484.0661

Hit 4 annotations: Iodiconazole_[M]+; methyl 3,4,5-trihydroxy-2-{6,7,13,14-tetrahydroxy-3,10-dioxo-2,9-dioxatetracyclo[6.6.2.0⁴,¹⁶.0¹¹,¹⁵]hexadeca-1(14),4(16),5,7,11(15),12-hexaen-5-yl}benzoate_[M-H2O+NH4]+; Penoxsulam_[M+H]+; carlliiionaln_[M+NH4]+

在BioDeep NovoCell知识数据库中，参考离子总共被划分为4个级别。

Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
Unreliable: 这个参考离子具有较高的排名价值，但缺乏可重复性。
Unavailable: 由于排名价值低且缺乏可重复性，这个参考离子不应用于注释。

Found 9 Reference Ions Near m/z 484.0661

NovoCell ID	m/z	Mass Window	Metabolite	Ranking	Anatomy Context
MSI_000017954 Reliable	484.057	484.057 ~ 484.057 MzDiff: `0.1 ppm`	methyl 3,4,5-trihydroxy-2-{6,7,13,14-tetrahydroxy-3,10-dioxo-2,9-dioxatetracyclo[6.6.2.0⁴,¹⁶.0¹¹,¹⁵]hexadeca-1(14),4(16),5,7,11(15),12-hexaen-5-yl}benzoate (BioDeep_00002067176) Formula: C22H12O13 (484.0278)	0.9 (100%)	Vitis vinifera [PO:0009087] mesocarp
MSI_000018084 Reliable	484.0623	484.0623 ~ 484.0623 MzDiff: `0.1 ppm`	Not Annotated	0.51 (0%)	Vitis vinifera [PO:0009087] mesocarp
MSI_000010833 Unreliable	484.0661	484.0661 ~ 484.0661 MzDiff: `none`	Iodiconazole (BioDeep_00000180046) Formula: C19H19F2IN4O (484.0572)	3.1 (100%)	Mus musculus [UBERON:0012378] muscle layer of urinary bladder
MSI_000010939 Unreliable	484.0731	484.0731 ~ 484.0731 MzDiff: `none`	Penoxsulam (BioDeep_00000002236) Formula: C16H14F5N5O5S (483.0636)	2.85 (100%)	Mus musculus [UBERON:0012378] muscle layer of urinary bladder
MSI_000009612 Unavailable	484.0731	484.0731 ~ 484.0731 MzDiff: `none`	Penoxsulam (BioDeep_00000002236) Formula: C16H14F5N5O5S (483.0636)	-1.1 (100%)	Mus musculus [UBERON:0004645] urinary bladder urothelium
MSI_000009815 Unavailable	484.0661	484.0661 ~ 484.0661 MzDiff: `none`	Iodiconazole (BioDeep_00000180046) Formula: C19H19F2IN4O (484.0572)	-1.73 (100%)	Mus musculus [UBERON:0004645] urinary bladder urothelium
MSI_000017722 Unreliable	484.0583	484.0583 ~ 484.0583 MzDiff: `none`	methyl 3,4,5-trihydroxy-2-{6,7,13,14-tetrahydroxy-3,10-dioxo-2,9-dioxatetracyclo[6.6.2.0⁴,¹⁶.0¹¹,¹⁵]hexadeca-1(14),4(16),5,7,11(15),12-hexaen-5-yl}benzoate (BioDeep_00002067176) Formula: C22H12O13 (484.0278)	1.6 (100%)	Vitis vinifera [PO:0009087] mesocarp
MSI_000016639 Unreliable	484.0583	484.0583 ~ 484.0583 MzDiff: `none`	methyl 3,4,5-trihydroxy-2-{6,7,13,14-tetrahydroxy-3,10-dioxo-2,9-dioxatetracyclo[6.6.2.0⁴,¹⁶.0¹¹,¹⁵]hexadeca-1(14),4(16),5,7,11(15),12-hexaen-5-yl}benzoate (BioDeep_00002067176) Formula: C22H12O13 (484.0278)	0.33 (100%)	Vitis vinifera [PO:0009086] endocarp
MSI_000016684 Unreliable	484.057	484.057 ~ 484.057 MzDiff: `none`	methyl 3,4,5-trihydroxy-2-{6,7,13,14-tetrahydroxy-3,10-dioxo-2,9-dioxatetracyclo[6.6.2.0⁴,¹⁶.0¹¹,¹⁵]hexadeca-1(14),4(16),5,7,11(15),12-hexaen-5-yl}benzoate (BioDeep_00002067176) Formula: C22H12O13 (484.0278)	0.24 (100%)	Vitis vinifera [PO:0009086] endocarp

Found 7 Sample Hits

Metabolite	Species	Sample
Iodiconazole Formula: C19H19F2IN4O (484.0572) Adducts: [M]+ (Ppm: 19.6)	Mus musculus (Urinary bladder)	HR2MSI_mouse_urinary_bladder - S096 Resolution: 10μm, 260x134 Description Mass spectrometry imaging of phospholipids in mouse urinary bladder (imzML dataset) The spatial distribution of phospholipids in a tissue section of mouse urinary bladder was analyzed by MALDI MS imaging at 10 micrometer pixel size with high mass resolution (using an LTQ Orbitrap mass spectrometer). R, ö, mpp A, Guenther S, Schober Y, Schulz O, Takats Z, Kummer W, Spengler B, Histology by mass spectrometry: label-free tissue characterization obtained from high-accuracy bioanalytical imaging. Angew Chem Int Ed Engl, 49(22):3834-8(2010) Fig. S2: Single ion images of compounds shown in Fig. 1A-B : (upper left to lower right) m/z = 743.5482 (unknown), m/z = 741.5307 (SM (16:0), [M+K]+), m/z = 798.5410 (PC (34:1), [M+K]+), m/z = 616.1767 (heme b, M+), m/z = 772.5253 (PC (32:0), [M+K]+). Stability of determined mass values was in the range of +/- 1 ppm over 22 hours of measurement (Fig. S4), with a standard deviation of 0.56 ppm. Accuracy data were obtained during tissue scanning experiments by monitoring the mass signal at nominal mass 798. The internal lock mass function of the Orbitrap instrument was used for automatic calibration during imaging measurements, using the known matrix-related ion signals at m/z = 137.0233, m/z = 444.0925 and m/z = 716.1246.
m/z_484.0623 Formula: - (n/a) Adducts: (Ppm: 0)	Vitis vinifera (Fruit)	grape_dhb_91_1 Resolution: 50μm, 120x114 Description Grape berries fruit, condition: Ripe
methyl 3,4,5-trihydroxy-2-{6,7,13,14-tetrahydroxy-3,10-dioxo-2,9-dioxatetracyclo[6.6.2.0⁴,¹⁶.0¹¹,¹⁵]hexadeca-1(14),4(16),5,7,11(15),12-hexaen-5-yl}benzoate Formula: C22H12O13 (484.0278) Adducts: [M-H2O+NH4]+ (Ppm: 15)	Vitis vinifera (Fruit)	grape_dhb_164_1 Resolution: 17μm, 136x122 Description Grape berries fruit, condition: Late
m/z_484.0623 Formula: - (n/a) Adducts: (Ppm: 0)	Vitis vinifera (Fruit)	grape_dhb_163_1 Resolution: 17μm, 132x115 Description Grape berries fruit, condition: Late
m/z_484.0748 Formula: - (n/a) Adducts: (Ppm: 0)	Posidonia oceanica (root)	MS1_20180404_PO_1200 Resolution: 17μm, 193x208 Description
Penoxsulam Formula: C16H14F5N5O5S (483.0636) Adducts: [M+H]+ (Ppm: 6.3)	Mytilus edulis (mantle)	20190201_MS38_Crassostrea_Mantle_350-1500_DHB_pos_A28_10um_270x210 Resolution: 10μm, 270x210 Description
carlliiionaln Formula: C12H14N6O10S2 (466.0213) Adducts: [M+NH4]+ (Ppm: 17.8)	Drosophila melanogaster (brain)	Drosophila18 Resolution: 5μm, 686x685 Description Sample information Organism: Drosophila melanogaster Organism part: Brain Condition: Healthy Sample preparation Sample stabilisation: Frozen Tissue modification: Frozen MALDI matrix: 2,5-dihydroxybenzoic acid (DHB) MALDI matrix application: TM sprayer Solvent: Aceton/water MS analysis Polarity: Positive Ionisation source: Prototype Analyzer: Orbitrap Pixel size: 5μm × 5μm Annotation settings m/z tolerance (ppm): 3 Analysis version: Original MSM Pixel count: 469910 Imzml file size: 696.23 MB Ibd file size: 814.11 MB