M/Z: 478.0235
Hit 3 annotations: Pesticide3_Hexaflumuron_C16H8Cl2F6N2O3__[M+NH4]+; N-[5-[[4-(1,1,1,3,3,3-Hexafluoro-2-hydroxypropan-2-yl)phenyl]sulfamoyl]-4-methyl-1,3-thiazol-2-yl]acetamide_[M+H]+; methyl 6-[(2r,3r,4r,5s)-5-[(3z,5z)-4,6-dibromohexa-3,5-dien-1-yl]-3-hydroxy-4-methoxyoxolan-2-yl]hex-5-ynoate_[M-H2O+NH4]+
- Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
- Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
- Unreliable: 这个参考离子具有较高的排名价值，但缺乏可重复性。
- Unavailable: 由于排名价值低且缺乏可重复性，这个参考离子不应用于注释。
Found 7 Reference Ions Near m/z 478.0235
| NovoCell ID | m/z | Mass Window | Metabolite | Ranking | Anatomy Context |
|---|---|---|---|---|---|
| MSI_000033674 Unreliable | 478.0292 | 478.0292 ~ 478.0292 MzDiff: none |
methyl 6-[(2r,3r,4r,5s)-5-[(3z,5z)-4,6-dibromohexa-3,5-dien-1-yl]-3-hydroxy-4-methoxyoxolan-2-yl]hex-5-ynoate (BioDeep_00002164341) Formula: C18H24Br2O5 (477.999) |
1.06 (100%) | Posidonia oceanica [PO:0005352] xylem |
| MSI_000035248 Unreliable | 478.0292 | 478.0292 ~ 478.0292 MzDiff: none |
methyl 6-[(2r,3r,4r,5s)-5-[(3z,5z)-4,6-dibromohexa-3,5-dien-1-yl]-3-hydroxy-4-methoxyoxolan-2-yl]hex-5-ynoate (BioDeep_00002164341) Formula: C18H24Br2O5 (477.999) |
0.85 (100%) | Posidonia oceanica [PO:0006203] pericycle |
| MSI_000037258 Unreliable | 478.0297 | 478.0297 ~ 478.0297 MzDiff: none |
methyl 6-[(2r,3r,4r,5s)-5-[(3z,5z)-4,6-dibromohexa-3,5-dien-1-yl]-3-hydroxy-4-methoxyoxolan-2-yl]hex-5-ynoate (BioDeep_00002164341) Formula: C18H24Br2O5 (477.999) |
1.97 (100%) | Posidonia oceanica [UBERON:0000329] hair root |
| MSI_000039889 Unreliable | 478.0297 | 478.0297 ~ 478.0297 MzDiff: none |
methyl 6-[(2r,3r,4r,5s)-5-[(3z,5z)-4,6-dibromohexa-3,5-dien-1-yl]-3-hydroxy-4-methoxyoxolan-2-yl]hex-5-ynoate (BioDeep_00002164341) Formula: C18H24Br2O5 (477.999) |
0.65 (100%) | Posidonia oceanica [PO:0005417] phloem |
| MSI_000012784 Unavailable | 478.0304 | 478.0304 ~ 478.0304 MzDiff: none |
N-[5-[[4-(1,1,1,3,3,3-Hexafluoro-2-hydroxypropan-2-yl)phenyl]sulfamoyl]-4-methyl-1,3-thiazol-2-yl]acetamide (BioDeep_00000183947) Formula: C15H13F6N3O4S2 (477.0252) |
-0.46 (100%) | Plant [PO:0005020] vascular bundle |
| MSI_000013813 Unreliable | 478.0304 | 478.0304 ~ 478.0304 MzDiff: none |
N-[5-[[4-(1,1,1,3,3,3-Hexafluoro-2-hydroxypropan-2-yl)phenyl]sulfamoyl]-4-methyl-1,3-thiazol-2-yl]acetamide (BioDeep_00000183947) Formula: C15H13F6N3O4S2 (477.0252) |
0.09 (100%) | Plant [PO:0005417] phloem |
| MSI_000018610 Unreliable | 478.0304 | 478.0304 ~ 478.0304 MzDiff: none |
N-[5-[[4-(1,1,1,3,3,3-Hexafluoro-2-hydroxypropan-2-yl)phenyl]sulfamoyl]-4-methyl-1,3-thiazol-2-yl]acetamide (BioDeep_00000183947) Formula: C15H13F6N3O4S2 (477.0252) |
1.7 (100%) | Plant [PO:0020124] root stele |
Found 4 Sample Hits
| Metabolite | Species | Sample | |
|---|---|---|---|
| Pesticide3_Hexaflumuron_C16H8Cl2F6N2O3_ Formula: C16H8Cl2F6N2O3 (459.9816) Adducts: [M+NH4]+ (Ppm: 16.9) |
Vitis vinifera (Fruit) |
grape_dhb_91_1Resolution: 50μm, 120x114
Grape berries fruit, condition: Ripe |
|
| Pesticide3_Hexaflumuron_C16H8Cl2F6N2O3_ Formula: C16H8Cl2F6N2O3 (459.9816) Adducts: [M+NH4]+ (Ppm: 15.6) |
Vitis vinifera (Fruit) |
grape_dhb_164_1Resolution: 17μm, 136x122
Grape berries fruit, condition: Late |
|
| N-[5-[[4-(1,1,1,3,3,3-Hexafluoro-2-hydroxypropan-2-yl)phenyl]sulfamoyl]-4-methyl-1,3-thiazol-2-yl]acetamide Formula: C15H13F6N3O4S2 (477.0252) Adducts: [M+H]+ (Ppm: 17) |
Mus musculus (Lung) |
image3Resolution: 40μm, 146x190
Fig. 4 MALDI-MSI data of mouse lung tissue after administration with D9-choline and U13C-DPPC–containing Poractant alfa surfactant (labels administered 12 h prior to tissue collection). Ion images of (A) m/z 796.6856 ([U13C-DPPC+Na]+), (B) m/z 756.5154 [PC32:0+Na]+), and (C) m/z 765.6079 ([D9-PC32:0+Na]+). D: Overlay image of [U13C-PC32:0+Na]+ (red) and [D9-PC32:0+Na]+ (green). Part-per-million (ppm) mass errors are indicated in parentheses. All images were visualized using total-ion-current normalization and using hotspot removal (high quantile = 99%). DPPC = PC16:0/16:0. MSI, mass spectrometry imaging; PC, phosphatidylcholine; U13C-DPPC, universally 13C-labeled dipalmitoyl PC. |
|
| methyl 6-[(2r,3r,4r,5s)-5-[(3z,5z)-4,6-dibromohexa-3,5-dien-1-yl]-3-hydroxy-4-methoxyoxolan-2-yl]hex-5-ynoate Formula: C18H24Br2O5 (477.999) Adducts: [M-H2O+NH4]+ (Ppm: 15.5) |
Posidonia oceanica (root) |
20190828_MS1_A19r-22Resolution: 17μm, 292x279
|
|
