M/Z: 478.0229

Hit 2 annotations: Pesticide3_Hexaflumuron_C16H8Cl2F6N2O3__[M+NH4]+; N-[5-[[4-(1,1,1,3,3,3-Hexafluoro-2-hydroxypropan-2-yl)phenyl]sulfamoyl]-4-methyl-1,3-thiazol-2-yl]acetamide_[M+H]+

在BioDeep NovoCell知识数据库中，参考离子总共被划分为4个级别。

Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
Unreliable: 这个参考离子具有较高的排名价值，但缺乏可重复性。
Unavailable: 由于排名价值低且缺乏可重复性，这个参考离子不应用于注释。

Found 7 Reference Ions Near m/z 478.0229

NovoCell ID	m/z	Mass Window	Metabolite	Ranking	Anatomy Context
MSI_000033674 Unreliable	478.0292	478.0292 ~ 478.0292 MzDiff: `none`	methyl 6-[(2r,3r,4r,5s)-5-[(3z,5z)-4,6-dibromohexa-3,5-dien-1-yl]-3-hydroxy-4-methoxyoxolan-2-yl]hex-5-ynoate (BioDeep_00002164341) Formula: C18H24Br2O5 (477.999)	1.06 (100%)	Posidonia oceanica [PO:0005352] xylem
MSI_000035248 Unreliable	478.0292	478.0292 ~ 478.0292 MzDiff: `none`	methyl 6-[(2r,3r,4r,5s)-5-[(3z,5z)-4,6-dibromohexa-3,5-dien-1-yl]-3-hydroxy-4-methoxyoxolan-2-yl]hex-5-ynoate (BioDeep_00002164341) Formula: C18H24Br2O5 (477.999)	0.85 (100%)	Posidonia oceanica [PO:0006203] pericycle
MSI_000037258 Unreliable	478.0297	478.0297 ~ 478.0297 MzDiff: `none`	methyl 6-[(2r,3r,4r,5s)-5-[(3z,5z)-4,6-dibromohexa-3,5-dien-1-yl]-3-hydroxy-4-methoxyoxolan-2-yl]hex-5-ynoate (BioDeep_00002164341) Formula: C18H24Br2O5 (477.999)	1.97 (100%)	Posidonia oceanica [UBERON:0000329] hair root
MSI_000039889 Unreliable	478.0297	478.0297 ~ 478.0297 MzDiff: `none`	methyl 6-[(2r,3r,4r,5s)-5-[(3z,5z)-4,6-dibromohexa-3,5-dien-1-yl]-3-hydroxy-4-methoxyoxolan-2-yl]hex-5-ynoate (BioDeep_00002164341) Formula: C18H24Br2O5 (477.999)	0.65 (100%)	Posidonia oceanica [PO:0005417] phloem
MSI_000012784 Unavailable	478.0304	478.0304 ~ 478.0304 MzDiff: `none`	N-[5-[[4-(1,1,1,3,3,3-Hexafluoro-2-hydroxypropan-2-yl)phenyl]sulfamoyl]-4-methyl-1,3-thiazol-2-yl]acetamide (BioDeep_00000183947) Formula: C15H13F6N3O4S2 (477.0252)	-0.46 (100%)	Plant [PO:0005020] vascular bundle
MSI_000013813 Unreliable	478.0304	478.0304 ~ 478.0304 MzDiff: `none`	N-[5-[[4-(1,1,1,3,3,3-Hexafluoro-2-hydroxypropan-2-yl)phenyl]sulfamoyl]-4-methyl-1,3-thiazol-2-yl]acetamide (BioDeep_00000183947) Formula: C15H13F6N3O4S2 (477.0252)	0.09 (100%)	Plant [PO:0005417] phloem
MSI_000018610 Unreliable	478.0304	478.0304 ~ 478.0304 MzDiff: `none`	N-[5-[[4-(1,1,1,3,3,3-Hexafluoro-2-hydroxypropan-2-yl)phenyl]sulfamoyl]-4-methyl-1,3-thiazol-2-yl]acetamide (BioDeep_00000183947) Formula: C15H13F6N3O4S2 (477.0252)	1.7 (100%)	Plant [PO:0020124] root stele

Found 3 Sample Hits

Metabolite	Species	Sample
Pesticide3_Hexaflumuron_C16H8Cl2F6N2O3_ Formula: C16H8Cl2F6N2O3 (459.9816) Adducts: [M+NH4]+ (Ppm: 16.9)	Vitis vinifera (Fruit)	grape_dhb_91_1 Resolution: 50μm, 120x114 Description Grape berries fruit, condition: Ripe
Pesticide3_Hexaflumuron_C16H8Cl2F6N2O3_ Formula: C16H8Cl2F6N2O3 (459.9816) Adducts: [M+NH4]+ (Ppm: 15.6)	Vitis vinifera (Fruit)	grape_dhb_164_1 Resolution: 17μm, 136x122 Description Grape berries fruit, condition: Late
N-[5-[[4-(1,1,1,3,3,3-Hexafluoro-2-hydroxypropan-2-yl)phenyl]sulfamoyl]-4-methyl-1,3-thiazol-2-yl]acetamide Formula: C15H13F6N3O4S2 (477.0252) Adducts: [M+H]+ (Ppm: 17)	Mus musculus (Lung)	image3 Resolution: 40μm, 146x190 Description Fig. 4 MALDI-MSI data of mouse lung tissue after administration with D9-choline and U13C-DPPC–containing Poractant alfa surfactant (labels administered 12 h prior to tissue collection). Ion images of (A) m/z 796.6856 ([U13C-DPPC+Na]+), (B) m/z 756.5154 [PC32:0+Na]+), and (C) m/z 765.6079 ([D9-PC32:0+Na]+). D: Overlay image of [U13C-PC32:0+Na]+ (red) and [D9-PC32:0+Na]+ (green). Part-per-million (ppm) mass errors are indicated in parentheses. All images were visualized using total-ion-current normalization and using hotspot removal (high quantile = 99%). DPPC = PC16:0/16:0. MSI, mass spectrometry imaging; PC, phosphatidylcholine; U13C-DPPC, universally 13C-labeled dipalmitoyl PC.

Metabolite

Species

Sample

Pesticide3_Hexaflumuron_C16H8Cl2F6N2O3_

Formula: C16H8Cl2F6N2O3 (459.9816)
Adducts: [M+NH4]+ (Ppm: 16.9)

Vitis vinifera (Fruit)

grape_dhb_91_1

Resolution: 50μm, 120x114

Description

Grape berries fruit, condition: Ripe

Pesticide3_Hexaflumuron_C16H8Cl2F6N2O3_

Formula: C16H8Cl2F6N2O3 (459.9816)
Adducts: [M+NH4]+ (Ppm: 15.6)

Vitis vinifera (Fruit)

grape_dhb_164_1

Resolution: 17μm, 136x122

Description

Grape berries fruit, condition: Late

N-[5-[[4-(1,1,1,3,3,3-Hexafluoro-2-hydroxypropan-2-yl)phenyl]sulfamoyl]-4-methyl-1,3-thiazol-2-yl]acetamide

Formula: C15H13F6N3O4S2 (477.0252)
Adducts: [M+H]+ (Ppm: 17)

Mus musculus (Lung)

image3

Resolution: 40μm, 146x190

Description

Fig. 4 MALDI-MSI data of mouse lung tissue after administration with D9-choline and U13C-DPPC–containing Poractant alfa surfactant (labels administered 12 h prior to tissue collection). Ion images of (A) m/z 796.6856 ([U13C-DPPC+Na]+), (B) m/z 756.5154 [PC32:0+Na]+), and (C) m/z 765.6079 ([D9-PC32:0+Na]+). D: Overlay image of [U13C-PC32:0+Na]+ (red) and [D9-PC32:0+Na]+ (green). Part-per-million (ppm) mass errors are indicated in parentheses. All images were visualized using total-ion-current normalization and using hotspot removal (high quantile = 99%). DPPC = PC16:0/16:0. MSI, mass spectrometry imaging; PC, phosphatidylcholine; U13C-DPPC, universally 13C-labeled dipalmitoyl PC.