M/Z: 429.0558

Hit 2 annotations: CDP-ethanolamine_[M+H-H2O]+; Cloransulam-methyl_[M-H2O+NH4]+

在BioDeep NovoCell知识数据库中，参考离子总共被划分为4个级别。

Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
Unreliable: 这个参考离子具有较高的排名价值，但缺乏可重复性。
Unavailable: 由于排名价值低且缺乏可重复性，这个参考离子不应用于注释。

Found 6 Reference Ions Near m/z 429.0558

NovoCell ID	m/z	Mass Window	Metabolite	Ranking	Anatomy Context
MSI_000053851 Unreliable	429.0581	429.0581 ~ 429.0582 MzDiff: `0.4 ppm`	CDP-ethanolamine (BioDeep_00000004450) Formula: C11H20N4O11P2 (446.0604)	4.1 (100%)	MALDI - CHCA [NOVOCELL:BACKGROUND] blank
MSI_000013220 Unavailable	429.0585	429.0585 ~ 429.0585 MzDiff: `none`	CDP-ethanolamine (BioDeep_00000004450) Formula: C11H20N4O11P2 (446.0604)	-0.85 (100%)	Plant [PO:0005020] vascular bundle
MSI_000013816 Unreliable	429.0585	429.0585 ~ 429.0585 MzDiff: `none`	CDP-ethanolamine (BioDeep_00000004450) Formula: C11H20N4O11P2 (446.0604)	0.08 (100%)	Plant [PO:0005417] phloem
MSI_000015015 Unavailable	429.0585	429.0585 ~ 429.0585 MzDiff: `none`	CDP-ethanolamine (BioDeep_00000004450) Formula: C11H20N4O11P2 (446.0604)	-0.52 (100%)	Plant [PO:0006036] root epidermis
MSI_000018629 Unreliable	429.0585	429.0585 ~ 429.0585 MzDiff: `none`	CDP-ethanolamine (BioDeep_00000004450) Formula: C11H20N4O11P2 (446.0604)	1.69 (100%)	Plant [PO:0020124] root stele
MSI_000019788 Unavailable	429.0585	429.0585 ~ 429.0585 MzDiff: `none`	CDP-ethanolamine (BioDeep_00000004450) Formula: C11H20N4O11P2 (446.0604)	-0.4 (100%)	Plant [PO:0025197] stele

Found 10 Sample Hits

Metabolite	Species	Sample
CDP-ethanolamine Formula: C11H20N4O11P2 (446.0604) Adducts: [M+H-H2O]+ (Ppm: 3.3)	Plant (Root)	MPIMM_035_QE_P_PO_6pm Resolution: 30μm, 165x170 Description
CDP-ethanolamine Formula: C11H20N4O11P2 (446.0604) Adducts: [M+H-H2O]+ (Ppm: 1.2)	Homo sapiens (Liver)	20171107_FIT4_DHBpos_p70_s50 Resolution: 50μm, 70x70 Description
CDP-ethanolamine Formula: C11H20N4O11P2 (446.0604) Adducts: [M+H-H2O]+ (Ppm: 3)	Vitis vinifera (Fruit)	grape_dhb_91_1 Resolution: 50μm, 120x114 Description Grape berries fruit, condition: Ripe
CDP-ethanolamine Formula: C11H20N4O11P2 (446.0604) Adducts: [M+H-H2O]+ (Ppm: 3)	Vitis vinifera (Fruit)	grape_dhb_163_1 Resolution: 17μm, 132x115 Description Grape berries fruit, condition: Late
Cloransulam-methyl Formula: C15H13ClFN5O5S (429.031) Adducts: [M-H2O+NH4]+ (Ppm: 1.5)	Mus musculus (Lung)	image4 Resolution: 40μm, 162x156 Description Fig 6c Fig. 6 MALDI-MSI of U13C-PC16:0/16:0 acyl chain remodeling. A: Averaged MALDI mass spectrum from lung tissue collected from mice euthanized 12 h after administration of D9-choline and U13C-DPPC–containing Poractant alfa surfactant. The ion at m/z 828.6321 is assigned as the [M+Na]+ ion of 13C24-PC16:0_20:4 formed by acyl remodeling of U13C-PC16:0/16:0. The “NL” value refers to the intensity of the base peak in the full range MS1 spectrum. B: MS/MS spectrum of precursor ions at m/z 828.5 ± 0.5 with fragment ions originating from [13C24-PC16:0_20:4+Na]+ annotated. Part-per-million (ppm) mass errors are provided in parentheses. C, D: MALDI-MSI data of [U13C-DPPC+Na]+ (blue), [PC36:4+Na]+ (green) and [13C24-PC16:0_20:4+Na]+ (red) in lung tissue collected from mice (C) 12 h and (D) 18 h after label administration. All images were visualized using total-ion-current normalization and hotspot removal (high quantile = 99%). MS/MS, tandem mass spectrometry; MSI, mass spectrometry imaging; PC, phosphatidylcholine; U13C-DPPC, universally 13C-labeled dipalmitoyl PC.
CDP-ethanolamine Formula: C11H20N4O11P2 (446.0604) Adducts: [M+H-H2O]+ (Ppm: 2.4)	Posidonia oceanica (root)	MS1_20180404_PO_1200 Resolution: 17μm, 193x208 Description
CDP-ethanolamine Formula: C11H20N4O11P2 (446.0604) Adducts: [M+H-H2O]+ (Ppm: 2.8)	Mytilus edulis (mantle)	20190201_MS38_Crassostrea_Mantle_350-1500_DHB_pos_A28_10um_270x210 Resolution: 10μm, 270x210 Description
CDP-ethanolamine Formula: C11H20N4O11P2 (446.0604) Adducts: [M+H-H2O]+ (Ppm: 1.9)	Mytilus edulis (gill)	20190202_MS38_Crassostrea_Gill_350-1500_DHB_pos_A25_11um_305x210 Resolution: 11μm, 305x210 Description single cell layer `class_4` is the gill structure cells, metabolite ion 534.2956 is the top representive ion of this type of cell
CDP-ethanolamine Formula: C11H20N4O11P2 (446.0604) Adducts: [M+H-H2O]+ (Ppm: 2.6)	Mytilus edulis (mantle)	20190216_MS38_Mytilus_mantle_350-1500_DHB_pos_A26_10um_275x210 Resolution: 10μm, 275x210 Description
CDP-ethanolamine Formula: C11H20N4O11P2 (446.0604) Adducts: [M+H-H2O]+ (Ppm: 1)	Drosophila melanogaster (brain)	Drosophila18 Resolution: 5μm, 686x685 Description Sample information Organism: Drosophila melanogaster Organism part: Brain Condition: Healthy Sample preparation Sample stabilisation: Frozen Tissue modification: Frozen MALDI matrix: 2,5-dihydroxybenzoic acid (DHB) MALDI matrix application: TM sprayer Solvent: Aceton/water MS analysis Polarity: Positive Ionisation source: Prototype Analyzer: Orbitrap Pixel size: 5μm × 5μm Annotation settings m/z tolerance (ppm): 3 Analysis version: Original MSM Pixel count: 469910 Imzml file size: 696.23 MB Ibd file size: 814.11 MB