M/Z: 292.059

Hit 4 annotations: 16-hydroxy-3,5-dioxa-11-azapentacyclo[10.7.1.0²,⁶.0⁸,²⁰.0¹⁴,¹⁹]icosa-1,6,8,10,12(20),14,16,18-octaen-13-one_[M+H]+; Disulfoton_[M+NH4]+; Chlorosesamone_[M]+; Fluazifop_[M+H-2H2O]+

在BioDeep NovoCell知识数据库中，参考离子总共被划分为4个级别。

Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
Unreliable: 这个参考离子具有较高的排名价值，但缺乏可重复性。
Unavailable: 由于排名价值低且缺乏可重复性，这个参考离子不应用于注释。

Found 7 Reference Ions Near m/z 292.059

NovoCell ID	m/z	Mass Window	Metabolite	Ranking	Anatomy Context
MSI_000017301 Reliable	292.0556	292.0555 ~ 292.0556 MzDiff: `0.3 ppm`	16-hydroxy-3,5-dioxa-11-azapentacyclo[10.7.1.0²,⁶.0⁸,²⁰.0¹⁴,¹⁹]icosa-1,6,8,10,12(20),14,16,18-octaen-13-one (BioDeep_00002065202) Formula: C17H9NO4 (291.0532)	3.15 (100%)	Vitis vinifera [PO:0009087] mesocarp
MSI_000054297 Reliable	292.0535	292.0531 ~ 292.0539 MzDiff: `3.2 ppm`	Chlorosesamone (BioDeep_00000019789) Formula: C15H13ClO4 (292.0502)	2.78 (100%)	MALDI - CHCA [NOVOCELL:BACKGROUND] blank
MSI_000016310 Unreliable	292.0556	292.0555 ~ 292.0556 MzDiff: `0.3 ppm`	16-hydroxy-3,5-dioxa-11-azapentacyclo[10.7.1.0²,⁶.0⁸,²⁰.0¹⁴,¹⁹]icosa-1,6,8,10,12(20),14,16,18-octaen-13-one (BioDeep_00002065202) Formula: C17H9NO4 (291.0532)	1.96 (100%)	Vitis vinifera [PO:0009086] endocarp
MSI_000004189 Unreliable	292.0537	292.0537 ~ 292.0537 MzDiff: `none`	Ferulic acid 4-sulfate (BioDeep_00000025686) Formula: C10H10O7S (274.0147)	0.91 (100%)	Homo sapiens [UBERON:0002107] liver
MSI_000033347 Unreliable	292.0531	292.0531 ~ 292.0531 MzDiff: `none`	Chlorosesamone (BioDeep_00000019789) Formula: C15H13ClO4 (292.0502)	2.19 (100%)	Posidonia oceanica [PO:0005352] xylem
MSI_000037261 Unreliable	292.0529	292.0529 ~ 292.0529 MzDiff: `none`	Chlorosesamone (BioDeep_00000019789) Formula: C15H13ClO4 (292.0502)	1.97 (100%)	Posidonia oceanica [UBERON:0000329] hair root
MSI_000039852 Unreliable	292.0539	292.0539 ~ 292.0539 MzDiff: `none`	Chlorosesamone (BioDeep_00000019789) Formula: C15H13ClO4 (292.0502)	0.87 (100%)	Posidonia oceanica [PO:0005417] phloem

Found 13 Sample Hits

Metabolite	Species	Sample
16-hydroxy-3,5-dioxa-11-azapentacyclo[10.7.1.0²,⁶.0⁸,²⁰.0¹⁴,¹⁹]icosa-1,6,8,10,12(20),14,16,18-octaen-13-one Formula: C17H9NO4 (291.0532) Adducts: [M+H]+ (Ppm: 16.9)	Vitis vinifera (Fruit)	grape_dhb_91_1 Resolution: 50μm, 120x114 Description Grape berries fruit, condition: Ripe
Disulfoton Formula: C8H19O2PS3 (274.0285) Adducts: [M+NH4]+ (Ppm: 16.1)	Rattus norvegicus (Epididymis)	epik_dhb_head_ito08_43 Resolution: 17μm, 298x106 Description
16-hydroxy-3,5-dioxa-11-azapentacyclo[10.7.1.0²,⁶.0⁸,²⁰.0¹⁴,¹⁹]icosa-1,6,8,10,12(20),14,16,18-octaen-13-one Formula: C17H9NO4 (291.0532) Adducts: [M+H]+ (Ppm: 16.5)	Vitis vinifera (Fruit)	grape_dhb_163_1 Resolution: 17μm, 132x115 Description Grape berries fruit, condition: Late
Disulfoton Formula: C8H19O2PS3 (274.0285) Adducts: [M+NH4]+ (Ppm: 15.4)	Rattus norvegicus (Epididymis)	epik_dhb_head_ito08_47 Resolution: 17μm, 301x111 Description
Chlorosesamone Formula: C15H13ClO4 (292.0502) Adducts: [M]+ (Ppm: 14.4)	Posidonia oceanica (root)	MS1_20180404_PO_1200 Resolution: 17μm, 193x208 Description
Fluazifop Formula: C15H12F3NO4 (327.0718) Adducts: [M+H-2H2O]+ (Ppm: 7.1)	Homo sapiens (colorectal adenocarcinoma)	80TopL, 50TopR, 70BottomL, 60BottomR-profile Resolution: 17μm, 137x136 Description The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024).
Disulfoton Formula: C8H19O2PS3 (274.0285) Adducts: [M+NH4]+ (Ppm: 12.3)	Homo sapiens (esophagus)	TO31T Resolution: 75μm, 56x54 Description
Disulfoton Formula: C8H19O2PS3 (274.0285) Adducts: [M+NH4]+ (Ppm: 11)	Homo sapiens (esophagus)	LNTO22_1_7 Resolution: 75μm, 69x54 Description
Disulfoton Formula: C8H19O2PS3 (274.0285) Adducts: [M+NH4]+ (Ppm: 11.6)	Homo sapiens (esophagus)	LNTO30_7_2 Resolution: 75μm, 82x68 Description
Disulfoton Formula: C8H19O2PS3 (274.0285) Adducts: [M+NH4]+ (Ppm: 11.3)	Homo sapiens (colorectal adenocarcinoma)	240TopL, 210TopR, 230BottomL, 220BottomR-centroid Resolution: 50μm, 142x141 Description
Disulfoton Formula: C8H19O2PS3 (274.0285) Adducts: [M+NH4]+ (Ppm: 12)	Homo sapiens (colorectal adenocarcinoma)	160TopL,130TopR,150BottomL,140BottomR-centroid Resolution: 50μm, 142x136 Description
Disulfoton Formula: C8H19O2PS3 (274.0285) Adducts: [M+NH4]+ (Ppm: 12.7)	Homo sapiens (colorectal adenocarcinoma)	120TopL, 90TopR, 110BottomL, 100BottomR-centroid Resolution: 50μm, 132x136 Description
Fluazifop Formula: C15H12F3NO4 (327.0718) Adducts: [M+H-2H2O]+ (Ppm: 8.5)	Drosophila melanogaster (brain)	Drosophila18 Resolution: 5μm, 686x685 Description Sample information Organism: Drosophila melanogaster Organism part: Brain Condition: Healthy Sample preparation Sample stabilisation: Frozen Tissue modification: Frozen MALDI matrix: 2,5-dihydroxybenzoic acid (DHB) MALDI matrix application: TM sprayer Solvent: Aceton/water MS analysis Polarity: Positive Ionisation source: Prototype Analyzer: Orbitrap Pixel size: 5μm × 5μm Annotation settings m/z tolerance (ppm): 3 Analysis version: Original MSM Pixel count: 469910 Imzml file size: 696.23 MB Ibd file size: 814.11 MB