M/Z: 291.0565
Hit 4 annotations: Formononetin_[M+Na]+; Sedoheptulose 7-phosphate_[M+H]+; Parathion_[M-H2O+NH4]+; 4-Hydroxy-5-(3'-hydroxyphenyl)-valeric acid-3'-O-sulphate_[M+H]+
- Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
- Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
- Unreliable: 这个参考离子具有较高的排名价值，但缺乏可重复性。
- Unavailable: 由于排名价值低且缺乏可重复性，这个参考离子不应用于注释。
Found 18 Reference Ions Near m/z 291.0565
| NovoCell ID | m/z | Mass Window | Metabolite | Ranking | Anatomy Context |
|---|---|---|---|---|---|
| MSI_000052795 Reliable | 291.0485 | 291.0483 ~ 291.0488 MzDiff: 2.0 ppm |
Sedoheptulose 7-phosphate (BioDeep_00000001740) Formula: C7H15O10P (290.0403) |
11.02 (100%) | DESI [NOVOCELL:BACKGROUND] blank |
| MSI_000053841 Reliable | 291.0624 | 291.0623 ~ 291.0628 MzDiff: 2.0 ppm |
1-[2-(methylsulfanyl)-4H,9H-[1,3]thiazino[6,5-b]indol-4-yl]propan-2-one (BioDeep_00000622071) Formula: C14H14N2OS2 (290.0548) |
4.15 (62%) | MALDI - CHCA [NOVOCELL:BACKGROUND] blank |
| MSI_000017597 Reliable | 291.05 | 291.05 ~ 291.05 MzDiff: 0.0 ppm |
Feruloyltartaric acid (BioDeep_00000228465) Formula: C14H14O9 (326.0638) |
1.98 (100%) | Vitis vinifera [PO:0009087] mesocarp |
| MSI_000053494 Unreliable | 291.0565 | 291.0565 ~ 291.0565 MzDiff: none |
Parathion (BioDeep_00000001403) Formula: C10H14NO5PS (291.033) |
2.4 (100%) | DESI [NOVOCELL:BACKGROUND] blank |
| MSI_000003906 Unreliable | 291.0629 | 291.0629 ~ 291.0629 MzDiff: none |
Formononetin (BioDeep_00000000371) Formula: C16H12O4 (268.0736) |
1.36 (100%) | Homo sapiens [UBERON:0002107] liver |
| MSI_000004084 Unreliable | 291.0494 | 291.0494 ~ 291.0494 MzDiff: none |
Sedoheptulose 7-phosphate (BioDeep_00000001740) Formula: C7H15O10P (290.0403) |
1.06 (100%) | Homo sapiens [UBERON:0002107] liver |
| MSI_000012457 Unreliable | 291.0594 | 291.0594 ~ 291.0594 MzDiff: none |
Formononetin (BioDeep_00000000371) Formula: C16H12O4 (268.0736) |
0.7 (100%) | Plant [PO:0005020] vascular bundle |
| MSI_000012782 Unavailable | 291.0499 | 291.0499 ~ 291.0499 MzDiff: none |
Sedoheptulose 7-phosphate (BioDeep_00000001740) Formula: C7H15O10P (290.0403) |
-0.46 (100%) | Plant [PO:0005020] vascular bundle |
| MSI_000013926 Unavailable | 291.0594 | 291.0594 ~ 291.0594 MzDiff: none |
Formononetin (BioDeep_00000000371) Formula: C16H12O4 (268.0736) |
-0.09 (100%) | Plant [PO:0005417] phloem |
| MSI_000014211 Unavailable | 291.0499 | 291.0499 ~ 291.0499 MzDiff: none |
Sedoheptulose 7-phosphate (BioDeep_00000001740) Formula: C7H15O10P (290.0403) |
-0.4 (100%) | Plant [PO:0005417] phloem |
| MSI_000014841 Unavailable | 291.0499 | 291.0499 ~ 291.0499 MzDiff: none |
Sedoheptulose 7-phosphate (BioDeep_00000001740) Formula: C7H15O10P (290.0403) |
-0.46 (100%) | Plant [PO:0006036] root epidermis |
| MSI_000016369 Unreliable | 291.05 | 291.05 ~ 291.05 MzDiff: none |
Feruloyltartaric acid (BioDeep_00000228465) Formula: C14H14O9 (326.0638) |
1.07 (100%) | Vitis vinifera [PO:0009086] endocarp |
| MSI_000018228 Unreliable | 291.0499 | 291.0499 ~ 291.0499 MzDiff: none |
Sedoheptulose 7-phosphate (BioDeep_00000001740) Formula: C7H15O10P (290.0403) |
1.79 (100%) | Plant [PO:0020124] root stele |
| MSI_000018809 Unreliable | 291.0594 | 291.0594 ~ 291.0594 MzDiff: none |
Formononetin (BioDeep_00000000371) Formula: C16H12O4 (268.0736) |
1.3 (100%) | Plant [PO:0020124] root stele |
| MSI_000019828 Unavailable | 291.0499 | 291.0499 ~ 291.0499 MzDiff: none |
Sedoheptulose 7-phosphate (BioDeep_00000001740) Formula: C7H15O10P (290.0403) |
-0.46 (100%) | Plant [PO:0025197] stele |
| MSI_000033634 Unreliable | 291.0623 | 291.0623 ~ 291.0623 MzDiff: none |
1-[2-(methylsulfanyl)-4H,9H-[1,3]thiazino[6,5-b]indol-4-yl]propan-2-one (BioDeep_00000622071) Formula: C14H14N2OS2 (290.0548) |
1.23 (100%) | Posidonia oceanica [PO:0005352] xylem |
| MSI_000037145 Unreliable | 291.0491 | 291.0491 ~ 291.0491 MzDiff: none |
Feruloyltartaric acid (BioDeep_00000228465) Formula: C14H14O9 (326.0638) |
2.04 (100%) | Posidonia oceanica [UBERON:0000329] hair root |
| MSI_000039826 Unreliable | 291.049 | 291.049 ~ 291.049 MzDiff: none |
Feruloyltartaric acid (BioDeep_00000228465) Formula: C14H14O9 (326.0638) |
1.18 (100%) | Posidonia oceanica [PO:0005417] phloem |
Found 9 Sample Hits
| Metabolite | Species | Sample | |
|---|---|---|---|
| Formononetin Formula: C16H12O4 (268.0736) Adducts: [M+Na]+ (Ppm: 11.6) |
Plant (Root) |
MPIMM_035_QE_P_PO_6pmResolution: 30μm, 165x170
|
|
| Sedoheptulose 7-phosphate Formula: C7H15O10P (290.0403) Adducts: [M+H]+ (Ppm: 9.1) |
Rattus norvegicus (Epididymis) |
epik_dhb_head_ito08_48Resolution: 17μm, 294x107
|
|
| Sedoheptulose 7-phosphate Formula: C7H15O10P (290.0403) Adducts: [M+H]+ (Ppm: 2.5) |
Homo sapiens (colorectal adenocarcinoma) |
80TopL, 50TopR, 70BottomL, 60BottomR-profileResolution: 17μm, 137x136
The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024). |
|
| Parathion Formula: C10H14NO5PS (291.033) Adducts: [M-H2O+NH4]+ (Ppm: 0.7) |
Homo sapiens (colorectal adenocarcinoma) |
80TopL, 50TopR, 70BottomL, 60BottomR-profileResolution: 17μm, 137x136
The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024). |
|
| Parathion Formula: C10H14NO5PS (291.033) Adducts: [M-H2O+NH4]+ (Ppm: 0) |
Homo sapiens (colorectal adenocarcinoma) |
520TopL, 490TopR, 510BottomL, 500BottomR-profileResolution: 17μm, 147x131
The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024). |
|
| 4-Hydroxy-5-(3'-hydroxyphenyl)-valeric acid-3'-O-sulphate Formula: C11H14O7S (290.046) Adducts: [M+H]+ (Ppm: 1.7) |
Homo sapiens (colorectal adenocarcinoma) |
439TopL, 409TopR, 429BottomL, 419BottomR-profileResolution: 17μm, 157x136
The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024). |
|
| Parathion Formula: C10H14NO5PS (291.033) Adducts: [M-H2O+NH4]+ (Ppm: 0.6) |
Homo sapiens (NA) |
160TopL,130TopR,150BottomL,140BottomR-profileResolution: 17μm, 142x136
|
|
| Formononetin Formula: C16H12O4 (268.0736) Adducts: [M+Na]+ (Ppm: 18.5) |
Homo sapiens (colorectal adenocarcinoma) |
240TopL, 210TopR, 230BottomL, 220BottomR-centroidResolution: 50μm, 142x141
|
|
| Formononetin Formula: C16H12O4 (268.0736) Adducts: [M+Na]+ (Ppm: 19.5) |
Homo sapiens (colorectal adenocarcinoma) |
160TopL,130TopR,150BottomL,140BottomR-centroidResolution: 50μm, 142x136
|
|
