在BioDeep NovoCell知识数据库中,参考离子总共被划分为4个级别。
  • Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
  • Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
  • Unreliable: 这个参考离子具有较高的排名价值,但缺乏可重复性。
  • Unavailable: 由于排名价值低且缺乏可重复性,这个参考离子不应用于注释。

Found 4 Reference Ions Near m/z 276.9831
NovoCell ID m/z Mass Window Metabolite Ranking Anatomy Context
MSI_000032579 Unreliable 276.9874 276.9873 ~ 276.9875
MzDiff: 1.1 ppm
4-[2-(3,4-dichloro-1h-pyrrol-2-yl)-1,3-oxazol-5-yl]phenol (BioDeep_00002318554)
Formula: C13H8Cl2N2O2 (293.9963)
1.25 (50%) Posidonia oceanica
[PO:0005020] vascular bundle
MSI_000012400 Unreliable 276.9874 276.9874 ~ 276.9874
MzDiff: none
3,5-Bis(trifluoromethyl)benzoyl chloride (BioDeep_00000174056)
Formula: C9H3ClF6O (275.9777)
1.25 (100%) Plant
[PO:0005020] vascular bundle
MSI_000018888 Unreliable 276.9874 276.9874 ~ 276.9874
MzDiff: none
3,5-Bis(trifluoromethyl)benzoyl chloride (BioDeep_00000174056)
Formula: C9H3ClF6O (275.9777)
0.92 (100%) Plant
[PO:0020124] root stele
MSI_000037628 Unreliable 276.9871 276.9871 ~ 276.9871
MzDiff: none
8-(2,2-dichloroacetyl)-5-hydroxy-2,7-dimethylnaphthalene-1,4-dione (BioDeep_00002235645)
Formula: C14H10Cl2O4 (311.9956)
0.62 (100%) Posidonia oceanica
[UBERON:0000329] hair root

Found 6 Sample Hits
Metabolite Species Sample
3,5-Bis(trifluoromethyl)benzoyl chloride

Formula: C9H3ClF6O (275.9777)
Adducts: [M+H]+ (Ppm: 6.6)
Marker Pen (NA)
3ul_0.8Mpa_RAW_20241016-PAPER PNMK
Resolution: 30μm, 315x42

Description

By writing the four English letters “PNMK” on white paper with a marker pen, and then scanning with a DESI ion source to obtain the scanning result. The signal of the chemical substances on the marker pen used appears on the channel with an m/z value of 322.1918, 323.1953, 546.4010, and etc, from the single cell deconvolution sampling layer class_4. This test data was tested by chuxiaoping from PANOMIX’s R&D laboratory.

3,5-Bis(trifluoromethyl)benzoyl chloride

Formula: C9H3ClF6O (275.9777)
Adducts: [M+H]+ (Ppm: 8.9)
Plant (Root)
MPIMM_035_QE_P_PO_6pm
Resolution: 30μm, 165x170

Description

8-(2,2-dichloroacetyl)-5-hydroxy-2,7-dimethylnaphthalene-1,4-dione

Formula: C14H10Cl2O4 (311.9956)
Adducts: [M+H-2H2O]+ (Ppm: 18.9)
Posidonia oceanica (root)
20190614_MS1_A19r-20
Resolution: 17μm, 262x276

Description

Seagrasses are one of the most efficient natural sinks of carbon dioxide (CO2) on Earth. Despite covering less than 0.1% of coastal regions, they have the capacity to bury up to 10% of marine organic matter and can bury the same amount of carbon 35 times faster than tropical rainforests. On land, the soil’s ability to sequestrate carbon is intimately linked to microbial metabolism. Despite the growing attention to the link between plant production, microbial communities, and the carbon cycle in terrestrial ecosystems, these processes remain enigmatic in the sea. Here, we show that seagrasses excrete organic sugars, namely in the form of sucrose, into their rhizospheres. Surprisingly, the microbial communities living underneath meadows do not fully use this sugar stock in their metabolism. Instead, sucrose piles up in the sediments to mM concentrations underneath multiple types of seagrass meadows. Sediment incubation experiments show that microbial communities living underneath a meadow use sucrose at low metabolic rates. Our metagenomic analyses revealed that the distinct community of microorganisms occurring underneath meadows is limited in their ability to degrade simple sugars, which allows these compounds to persist in the environment over relatively long periods of time. Our findings reveal how seagrasses form blue carbon stocks despite the relatively small area they occupy. Unfortunately, anthropogenic disturbances are threatening the long-term persistence of seagrass meadows. Given that these sediments contain a large stock of sugars that heterotopic bacteria can degrade, it is even more important to protect these ecosystems from degradation.

4-[2-(3,4-dichloro-1h-pyrrol-2-yl)-1,3-oxazol-5-yl]phenol

Formula: C13H8Cl2N2O2 (293.9963)
Adducts: [M+H-H2O]+ (Ppm: 19.8)
Posidonia oceanica (root)
20190613_MS1_A19r-18
Resolution: 17μm, 246x264

Description

8-(2,2-dichloroacetyl)-5-hydroxy-2,7-dimethylnaphthalene-1,4-dione

Formula: C14H10Cl2O4 (311.9956)
Adducts: [M+H-2H2O]+ (Ppm: 19.3)
Posidonia oceanica (root)
20190828_MS1_A19r-22
Resolution: 17μm, 292x279

Description

m/z_276.9873

Formula: - (n/a)
Adducts: (Ppm: 0)
Posidonia oceanica (root)
MS1_20180404_PO_1200
Resolution: 17μm, 193x208

Description