M/Z: 224.0679

Hit 2 annotations: (E)-Monocrotophos_[M+H]+; Skimmianine_[M+H-2H2O]+

在BioDeep NovoCell知识数据库中，参考离子总共被划分为4个级别。

Confirmed: 这个参考离子已经通过手动审计得到确认和验证。
Reliable: 这个参考离子可能在特定的解剖组织环境中高度保守。
Unreliable: 这个参考离子具有较高的排名价值，但缺乏可重复性。
Unavailable: 由于排名价值低且缺乏可重复性，这个参考离子不应用于注释。

Found 2 Reference Ions Near m/z 224.0679

NovoCell ID	m/z	Mass Window	Metabolite	Ranking	Anatomy Context
MSI_000057968 Reliable	224.0694	224.0692 ~ 224.0696 MzDiff: `1.5 ppm`	(E)-Monocrotophos (BioDeep_00000002080) Formula: C7H14NO5P (223.061)	4.38 (100%)	DESI [NOVOCELL:BACKGROUND] blank
MSI_000016932 Unavailable	224.0679	224.0679 ~ 224.0679 MzDiff: `none`	Skimmianine (BioDeep_00000017345) Formula: C14H13NO4 (259.0845)	-0.24 (100%)	Vitis vinifera [PO:0009086] endocarp

Found 14 Sample Hits

Metabolite	Species	Sample
(E)-Monocrotophos Formula: C7H14NO5P (223.061) Adducts: [M+H]+ (Ppm: 17.1)	Marker Pen (NA)	3ul_0.8Mpa_RAW_20241016-PAPER PNMK Resolution: 30μm, 315x42 Description By writing the four English letters “PNMK” on white paper with a marker pen, and then scanning with a DESI ion source to obtain the scanning result. The signal of the chemical substances on the marker pen used appears on the channel with an m/z value of `322.1918`, `323.1953`, `546.4010`, and etc, from the single cell deconvolution sampling layer `class_4`. This test data was tested by chuxiaoping from PANOMIX’s R&D laboratory.
Skimmianine Formula: C14H13NO4 (259.0845) Adducts: [M+H-2H2O]+ (Ppm: 12.1)	Vitis vinifera (Fruit)	grape_dhb_91_1 Resolution: 50μm, 120x114 Description Grape berries fruit, condition: Ripe
Skimmianine Formula: C14H13NO4 (259.0845) Adducts: [M+H-2H2O]+ (Ppm: 12.1)	Vitis vinifera (Fruit)	grape_dhb_163_1 Resolution: 17μm, 132x115 Description Grape berries fruit, condition: Late
(E)-Monocrotophos Formula: C7H14NO5P (223.061) Adducts: [M+H]+ (Ppm: 5.2)	Homo sapiens (esophagus)	LNTO22_1_3 Resolution: 75μm, 121x68 Description
(E)-Monocrotophos Formula: C7H14NO5P (223.061) Adducts: [M+H]+ (Ppm: 4.2)	Homo sapiens (esophagus)	LNTO22_1_4 Resolution: 17μm, 82x80 Description
(E)-Monocrotophos Formula: C7H14NO5P (223.061) Adducts: [M+H]+ (Ppm: 5.2)	Homo sapiens (colorectal adenocarcinoma)	80TopL, 50TopR, 70BottomL, 60BottomR-profile Resolution: 17μm, 137x136 Description The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024).
(E)-Monocrotophos Formula: C7H14NO5P (223.061) Adducts: [M+H]+ (Ppm: 5.2)	Homo sapiens (colorectal adenocarcinoma)	520TopL, 490TopR, 510BottomL, 500BottomR-profile Resolution: 17μm, 147x131 Description The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024).
(E)-Monocrotophos Formula: C7H14NO5P (223.061) Adducts: [M+H]+ (Ppm: 4.8)	Homo sapiens (colorectal adenocarcinoma)	439TopL, 409TopR, 429BottomL, 419BottomR-profile Resolution: 17μm, 157x136 Description The human colorectal adenocarcinoma sample was excised during a surgical operation performed at the Imperial College Healthcare NHS Trust. The sample and procedures were carried out in accordance with ethical approval (14/EE/0024).
(E)-Monocrotophos Formula: C7H14NO5P (223.061) Adducts: [M+H]+ (Ppm: 4.3)	Homo sapiens (esophagus)	LNTO29_16_3 Resolution: 17μm, 108x107 Description
(E)-Monocrotophos Formula: C7H14NO5P (223.061) Adducts: [M+H]+ (Ppm: 5.2)	Homo sapiens (esophagus)	TO29T Resolution: 75μm, 56x48 Description
(E)-Monocrotophos Formula: C7H14NO5P (223.061) Adducts: [M+H]+ (Ppm: 4.8)	Homo sapiens (esophagus)	LNTO22_1_7 Resolution: 75μm, 69x54 Description
(E)-Monocrotophos Formula: C7H14NO5P (223.061) Adducts: [M+H]+ (Ppm: 6.1)	Homo sapiens (esophagus)	LNTO22_1_8 Resolution: 75μm, 69x61 Description
(E)-Monocrotophos Formula: C7H14NO5P (223.061) Adducts: [M+H]+ (Ppm: 4.8)	Homo sapiens (esophagus)	LNTO22_2_1 Resolution: 75μm, 89x88 Description
(E)-Monocrotophos Formula: C7H14NO5P (223.061) Adducts: [M+H]+ (Ppm: 3.4)	Homo sapiens (colorectal adenocarcinoma)	240TopL, 210TopR, 230BottomL, 220BottomR-centroid Resolution: 50μm, 142x141 Description